过渡金属化合物催化合成环氧增塑剂研究进展  

Advances on synthesis of epoxy soybean oil plasticizer catalyzed by transition metal complexes

作　　者：门楠 白雪 邓桂春 金旗兵 李晓云 王景芸[1] MEN Nan;BAI Xue;DENG Gui-chun;JIN Qin-bing;LI Xiao-yun;WANG Jing-yun(College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University, Fushun 113001,China;Clean Energy Collaborative Innovation Center,Quanzhou Institute of Technology, Quanzhou 362268,China;Bengang Steel Plate Company Limited Coking Plant,Benxi 117000,China)

机构地区：[1]辽宁石油化工大学化学化工与环境学部,辽宁抚顺113001 [2]泉州理工学院清洁能源协同创新中心,福建泉州362268 [3]本钢板材股份有限公司焦化厂,辽宁本溪117000

出　　处：《应用化工》2019年第3期721-727,共7页Applied Chemical Industry

基　　金：辽宁省自然科学基金指导计划(20170540590);辽宁省教育厅基本科研项目(L2017LFW011);辽宁石油化工大学博士科研启动基金项目(2016XJJ-063)

摘　　要：从过渡金属元素化合物的元素种类、催化剂类型、反应条件以及反应机理等方面综述了过渡金属化合物催化剂催化制备环氧增塑剂的研究进展。文中提出了催化过程中存在的问题,并对未来的研究方向进行展望。This review summarizes the progress in the preparation of epoxide plasticizers catalyzed by transition metal compounds from the element types,types of catalysts,reaction conditions and reaction mechanism of the transition metal compounds.The problems existing in the catalysis process are pointed out,and the future research directions are prospected.

关 键 词：环氧增塑剂 过渡金属 催化 

分 类 号：TQ426.6[化学工程] O643.36[理学—物理化学]