The influence of the NCO/OH ratio and the 1,6-hexanediol/ dimethylol propionic acid molar ratio on the properties of waterborne polyurethane dispersions based on 1,5-pentamethylene diisocyanate  

作　　者：Jiao Feng Qiuhao Lu Weimin Tan Kequan Chen Pingkai Ouyang 

机构地区：[1]State Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211816, China [2]National Engineering Research Center for Coatings, CNOOC Changzhou Paint and Coatings Industry Research Institute Co., Ltd., Changzhou 213016, China

出　　处：《Frontiers of Chemical Science and Engineering》2019年第1期80-89,共10页化学科学与工程前沿（英文版）

基　　金：the National Natural Science Foundation of China (Grant Nos. 21576134 and 51503097);the National Key Research and Development Program of China (Grant No. 2016YFA0204300);the Jiangsu Province Natural Science Foundation (No. BK20150244).

摘　　要：1,5-Pentamethylene diisocyanate, a novel aliphatic diisocyanate formed from bio-based 1,5-pentamethylenediamine, has been used as a hard segmented material to synthesize polyurethane. In this study, several waterborne polyurethane (WPU) dispersions have been successfully prepared by a prepolymer process from 1,5-pentamethylene diisocyanate poly(polyether) with different NCO/OH ratios and 1,6-hexanediol (HDO)/dimethylol propionic acid (DMPA) molar ratios. The Fourier transfonn infrared (FTIR) spectra, thermogravimetric analysis, differential scanning calorimetry, X-ray diffiraction, and a mechanical tensile test were used to investigate the structures, thermal stability, phase separation, crystallinity, mechanical properties, and adhesive performance of the WPU dispersions. The FTIR results indicate that the degree of hydrogen bonding and the numbers of urea groups increase as the NCO/OH ratio and HDO/DMPA molar ratio increase. Furthermore, the phase separation increases and the thermal stability decreases as the NCO/OH ratio increases or the HDO/DMPA molar ratio decreases. Finally, WPU3.0-2.4 (NCO/OH = 3, HDO/DMPA = 2.4) exhibits a maximum tensile strength and shear strength, pointing to its possible use as an adhesive. These results could provide a very valuable reference for industrial applications of WPU.

关 键 词：1 5-pentamethylene DIISOCYANATE POLYURETHANE WATER based 

分 类 号：TQ[化学工程]