煤沥青中不溶组分对中间相炭微球形成的影响  

Effect of insoluble components in coal pitch on formation of mesophase carbon microspheres

作　　者：景介辉 林超群 张泽宇 王鹏 徐秀梅 吴大青 JING Jie-hui;UN Chao-qun;ZHANG Ze-yu;WANG Peng;XU Xiu-mei;WU Da-qing(College of Environmental and Chemical Engineering,Heilongjiang University of Science and Technology,Harbin 150022,China)

机构地区：[1]黑龙江科技大学环境与化工学院,哈尔滨150022

出　　处：《炭素》2019年第1期15-21,共7页Carbon

基　　金：黑龙江省教育厅科学技术研究项目(12541735)

摘　　要：以煤沥青为原料,采用热聚合方法制备中间相炭微球,研究热聚合温度370-385℃、聚合时间2h反应条件下煤沥青中喹啉不溶物、外添加氧化石墨烯对中间相炭微球形成的影响,结果表明:沥青中不溶物组分对中间相炭微球形成具有一定促进作用,在380℃热聚合条件下,能够制备出粒度分布较均匀、粒径为0.5μm-2.0μm的炭微球,而无喹啉不溶物的精制沥青,没有得到球形结构的碳材料。Mesophase carbon microspheres were prepared from coal tar pitch by thermal polymerization. The effects of quinoline insoluble substance in coal tar pitch and graphene oxide on the formation of mesophase carbon microspheres were studied under the conditions of thermal polymerization temperature of 370-385 and time of 2 hours. The results show that the insoluble substances in pitch can promote the formation of mesophase carbon microspheres to a certain extent. Carbon microspheres with uniform particle size distribution and 0.5-2.0 um particle size can be prepared at 380℃. While carbon materials with spherical structure can not be obtained by refined coal tar pitch without quinoline insoluble substance.

关 键 词：中温沥青 不溶组分 中间相炭微球 热聚合方法 

分 类 号：TQ552.65[化学工程]