粉煤灰基ZSM-5分子筛研究进展  

Research progress in preparation of ZSM-5 zeolite with fly ash

作　　者：王辉 臧亮鹏 朱鋆珊 赵彩云[1] 刘晓玲 WANG Hui;ZANG Liangpeng;ZHU Yunshan;ZHAO Caiyun;LIU Xiaoling(School of Chemical and Biological Engineering,Yinchuan University,Yinchuan 750100,China;Beijing YNE Power Water-treatment Engineering Co.Ltd., Beijing 100000,China;Northwest Institute of Mechanical Technician,Ningxia Institute of Technology,Shizuishan 753000,China)

机构地区：[1]银川能源学院化学与生物工程学院,宁夏银川750100 [2]北京英纳尔电力水处理工程技术有限责任公司,北京100000 [3]宁夏工业学校西北机械技师学院,宁夏石嘴山753000

出　　处：《化工科技》2019年第2期70-73,共4页Science & Technology in Chemical Industry

基　　金：宁夏回族自治区十三五重点专业建设(能源化学工程专业子项目);银川能源学院校级大学生创新项目(12018-DCX005)

摘　　要：对粉煤灰利用现状,粉煤灰的前处理,粉煤灰为原料合成ZSM-5分子筛和表征方法及其在化工领域中的应用进行了综述。通过对比水热合成法、一步法、两步法、碱熔法及浸渍法,得出水热法是较为理想的合成方法。采用X射线衍射(XRD)表征ZSM-5分子筛的物相,扫描电子显微镜(SEM)观察形貌,NH_3-程序升温脱附(NH_3-TPD)分析催化剂的酸强度,并对ZSM-5分子筛的合成及应用前景进行了展望。The utilization of fly ash,the pretreatment of fly ash,the preparation and characterization methods of ZSM-5 by fly ash and their application in the chemical industry were reviewed.By comparing with hydrothermal method,one-step method,two-step method,alkali melting method and impregnation method,two-step hydrothermal method was an ideal synthesis method.The phase of ZSM-5 molecular sieve was characterized by XRD,the morphology was observed by SEM,and the calculated acid strength of catalyst was analyzed by NH 3-TPD.The development prospect of ZSM-5 was also elucidated.

关 键 词：ZSM-5分子筛 粉煤灰 合成 

分 类 号：TQ426[化学工程]