蒽醌合成工艺研究进展  

Progress in Synthesis of Anthraquinone

作　　者：王尔泽 王欣[1] 陈平[1] Wang Erze;Wang Xin;Chen Ping(College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,Fushun Liaoning 113001,China)

机构地区：[1]辽宁石油化工大学化学化工与环境学部,辽宁抚顺113001

出　　处：《辽宁石油化工大学学报》2019年第2期15-20,共6页Journal of Liaoning Petrochemical University

基　　金：国家自然科学基金项目(21071073);辽宁省自然科学基金项目(2015020196)

摘　　要：综述了近十年合成蒽醌(AQ)及其衍生物的工艺技术,详细阐述了由蒽(AN)制蒽醌的氧化法和苯酐法工艺条件,分析了蒽氧化制蒽醌的机理,进一步介绍了一步法和两步法由苯酐合成蒽醌催化剂的应用,着重介绍了沸石分子筛和强酸性离子液体作为催化剂在一步法或两步法合成蒽醌中的应用,并对未来蒽醌合成工艺的开发提出建议。Synthetic technology of anthraquinone (AQ) and its derivatives in the past ten years was reviewed. The process conditions of anthraquinone production from anthracene (AN) by oxidation and phthalic anhydride were described in detail. The mechanism of anthraquinone oxidation by anthracene oxidation was analyzed. The application of one-step and two-step synthesis of ruthenium catalyst from phthalic anhydride was introduced. Especially, the application and development of zeolites and strong acidic ionic liquids as catalysts was introduced in the anthraquinone synthesis process by one - step or two - step, and have suggestions for the development of future antimony synthesis processes.

关 键 词：蒽醌 苯酐法 蒽氧化 绿色合成 

分 类 号：TQ244.63[化学工程—有机化工]