锰氮掺杂的碳材料催化苄基醚氧化生成酯（英文）  

α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst

作　　者：刘晶 万聪 郑爱丽 王连月[2] 殷凯越 刘丹丹 王圣德 任兰会 高爽[2] Liu Jing;Wan Cong;Zheng Aili;Wang Lianyue;Yin Kaiyue;Liu Dandan;Wang Shengde;Ren Lanhui;Gao Shuang(College of Pharmacy,Weifang Medical University,Weifang 261053;Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023)

机构地区：[1]潍坊医学院药学院,潍坊261053 [2]中国科学院大连化学物理研究所,大连116023

出　　处：《有机化学》2019年第3期811-820,共10页Chinese Journal of Organic Chemistry

基　　金：Project supported by the National Natural Science Foundation of China(Nos.21773227,21773232)~~

摘　　要：报道了一种在无溶剂条件下可回收的锰氮掺杂的碳材料催化叔丁基过氧化氢氧化苄基醚生成酯的催化氧化体系.该催化氧化体系具有好的官能团耐受性、优异的化学选择性,而且该催化氧化体系可以放大.A catalytic system for the oxidation of benzylic ethers to esters has been developed utilizing reusable MnOx-N@C as catalyst and tert-butyl hydroperoxide (TBHP) as benign oxidant under neat condition. The catalytic oxidation system has good functional groups tolerance and excellent chemoselectivity, and this catalytic procedure can also be scaled up.

关 键 词：C-H键 氧化 醚 酯 无溶剂 

分 类 号：O621.251[理学—有机化学] TQ225.24[理学—化学]