一种铜基二维金属-有机框架材料的合成与结构表征  

Synthesis and Characterization of a 2D Copper(Ⅱ)-based Metal Organic-framework

作　　者：李昌达 胡圆圆 杨可可 汤海同 李德 张艳华 朱成峰 LI Chang-da;HU Yuan-yuan;YANG Ke-ke;TANG Hai-tong;LI De;ZHANG Yan-hua;ZHU Cheng-feng(College of Chemistry and Chemical Engineering, Hefei University ofTechnology, Hefei 230009, China;Anhui Vocational College of Defense Technology, Lu' an 237011,China)

机构地区：[1]合肥工业大学化学与化工学院,安徽合肥230009 [2]安徽省国防科技职业学院,安徽六安237011

出　　处：《安徽化工》2019年第2期48-49,53,共3页Anhui Chemical Industry

摘　　要：以1,3,5-三溴苯为初始原料,设计合成了一种V形结构的刚性桥联配体L-H_2,并利用水热-溶剂热反应与铜离子合成了一种具有二维结构的铜基金属-有机框架材料,其结构通过X-射线单晶/粉末衍射以及红外光谱等技术进行了表征。A rigid bridging ligand L-H2 with V-shaped structure was designed and synthesized by using 1,3,5-tribromobenzene as the starting material, which was employed to prepare a Cu-based coordination polymers. The structure was characterized by IR, single and powder X-ray diffraction.

关 键 词：1 3 5-三溴苯 桥联配体 铜离子 金属有机-框架材料 晶体结构 

分 类 号：O643.36[理学—物理化学] O644.1[理学—化学]