Brazeability evaluation of Ti-Zr-Cu-Ni-Co-Mo filler for vacuum brazing TiAl-based alloy  

真空钎焊TiAl基合金用Ti-Zr-Cu-Ni-Co-Mo钎料的钎焊性能（英文）

作　　者：Li LI Xiao-qiang LI Ke HU Bo-lin HE Hua MAN 李力;李小强;胡可;何柏林;满华(华东交通大学材料科学与工程学院,南昌330013;华南理工大学国家金属材料近净成形工程技术研究中心,广州510640;广东省材料与加工研究所国家钛及稀有金属粉末冶金工程技术研究中心,广州510650)

机构地区：[1]School of Materials Science and Engineering,East China Jiaotong University,Nanchang 330013,China [2]National Engineering Research Center of Near-net-shape Forming for Metallic Materials,South China University of Technology,Guangzhou 510640,China [3]National Engineering Research Center of Powder Metallurgy of Titanium & Rare Metals,Guangdong Institute of Materials and Processing,Guangzhou 510650,China

出　　处：《Transactions of Nonferrous Metals Society of China》2019年第4期754-763,共10页中国有色金属学报（英文版）

基　　金：Foundation item:Project(51865012)supported by the National Natural Science Foundation of China;Project(2016005)supported by the Open Foundation of National Engineering Research Center of Near-net-shape Forming for Metallic Materials,China;Project(GJJ170372)supported by the Science Foundation of Educational Department of Jiangxi Province,China;Project(JCKY2016603C003)supported by the GF Basic Research Project,China;Project(JPPT125GH038)supported by the Research Project of Special Furnishment and Part,China

摘　　要：Ti-47Al-2Nb-2Cr-0.15B(mole fraction,%)alloy was vacuum brazed with amorphous and crystalline Ti.25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo(mass fraction,%)filler alloys,and the melting,spreading and gap filling behaviors of the amorphous and crystalline filler alloys as well as the joints brazed with them were investigated in details.Results showed that the amorphous filler alloy possessed narrower melting temperature interval,lower liquidus temperature and melting active energy compared with the crystalline filler alloy,and it also exhibited better brazeability on the surface of the Ti.47Al.2Nb.2Cr.0.15B alloy.The TiAl joints brazed with crystalline and amorphous filler alloys were composed of two interfacial reaction layers and a central brazed layer.Under the same conditions,the tensile strength of the joint brazed with the amorphous filler alloy was always higher than that with the crystalline filler alloy.The maxmium tensile strength of the joint brazed at 1273 K with the amorphous filler alloy reached 254 MPa.采用非晶和晶态Ti-25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo(质量分数,%)钎料对Ti-47Al-2Nb-2Cr-0.15B(摩尔分数,%)合金进行真空钎焊连接,对两种钎料的熔化行为、润湿铺展性、填缝隙能力以及由钎焊TiAl基合金所得的钎焊接头进行详细的研究。结果表明:与晶态钎料相比,非晶钎料具有更窄的熔化温度区间、更低的液相线温度和熔化激活能;同时,非晶钎料在Ti-47Al-2Nb-2Cr-0.15B合金表面上具有更优异的钎焊性。非晶和晶态两种钎料的钎焊接头均由两侧的界面反应层和中心钎焊层组成,非晶钎料钎焊接头的抗拉强度均高于相同钎焊工艺参数下的晶态钎料钎焊接头的抗拉强度,且在钎焊温度1273K下获得的钎焊接头的抗拉强度达到最大值254 MPa。

关 键 词：vacuum brazing Ti.47Al.2Nb.2Cr.0.15B alloy amorphous Ti-25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo filler alloy tensile strength interfacial microstructure brazeability 

分 类 号：TG454[金属学及工艺—焊接]