均苯三甲酸金属配合物的合成研究  

The Synthesis Research of Metal Complexes Based on 1,3,5-benzenetricarboxylic Acid

作　　者：李浩源 汤一丰 李宗键 刘传生 叶领云 谭桂平 Li Haoyuan;Tang Yifeng;Li Zongjian;Liu Chuansheng;Ye Lingyun;Tan Guiping(School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523808, China)

机构地区：[1]东莞理工学院生态环境与建筑工程学院,广东东莞523808

出　　处：《广东化工》2019年第8期108-109,共2页Guangdong Chemical Industry

基　　金：大学生创新创业训练计划立项省级项目

摘　　要：伴随着工业化程度的提高,国家工业生产力也日渐上升,随之能源消耗也日渐增大,除了一些环保清洁能源如:氢能、太阳能、风能、水力发电等,许多其他传统能源如煤炭、燃油等,燃烧后会生成破坏自然环境的颗粒物和有害气体。含硫化合物一直是燃油中难以祛除的部分,且含硫化合物对环境的危害相当严重,所以研究如何祛除燃油中含硫化合物具有重大意义。金属-有机框架材料(MOFs)是一种由有机配体和金属阳离子通过配位组合在一起的材料,它的排列规则,整齐有序,孔洞结构方面都具有力学的稳定性,均苯三甲酸金属配合物即具有这种性质,由金属阳离子和1,3,5苯三甲酸根按照一定比例通过配位聚合而形成的,具有稳定的孔道结构,可应用在燃油中含硫化合物的吸附分离。As the development of industrialization, the industrial production of our country is increasing, with the increase of energy consumption, besides the environment-friendly energy as the solar energy, wind energy and hydroelectric power, other energy such as coal and fuel will generate partical and harmful gas, leading to environmental pollution. The sulphocompounds in the fuel are very difficult to remove, and they will turn into harmful pollutant after burning, so, it is significant to investigate the removement of sulphocompounds in fuel. Metal-organic frameworks(MOFs) is a kind of materials combined by coordination with organic ligands and metal ions, they arrange regularly and orderly, their porous structures are mechanical stable, which are also the properties of 1,3,5-Benzenetricarboxylic metal complexes, coordinating by metal ions and 1,3,5-Benzenetricarboxylic acid with a certain ratio, with stable porous structures, may apply in the adsorption and separation of sulphocompounds from fuel.

关 键 词：金属-有机框架化合物 均苯三甲酸 合成 

分 类 号：TQ213[化学工程—有机化工]