The effect of monosaccharides on self-assembly of benzenetricarboxamides  

作　　者：Jue Wang Wenjing Qi Guosong Chen 

机构地区：[1]The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University

出　　处：《Chinese Chemical Letters》2019年第3期587-591,共5页中国化学快报（英文版）

基　　金：The Ministry of Science and Technology of China and the National Natural Science Foundation of China(Nos.91527305 and 51322306)are acknowledged for their financial support

摘　　要：The interaction between monosaccharides exhibits an important role in the assembly of monosaccharide-containing molecules. In this work, three common monosaccharides, glucose, galactose and mannose, are employed to investigate the effect of monosaccharide on the self-assembly of benzenetricarboxamide(BTA) core-containing molecules. In the presence of monosaccharides, three benzenetricarboxamide derivatives aggregate into different ordered structures. When alanine linkers are introduced to these molecules between the core and the monosacchride, morphologies of three types of monosaccharide BTAs turned to disordered, meanwhile their structures become similar with the increase of the length of alanine linkers, indicating the disappearance of the monosaccharide effects.The interaction between monosaccharides exhibits an important role in the assembly of monosaccharide-containing molecules. In this work, three common monosaccharides, glucose, galactose and mannose, are employed to investigate the effect of monosaccharide on the self-assembly of benzenetricarboxamide(BTA) core-containing molecules. In the presence of monosaccharides, three benzenetricarboxamide derivatives aggregate into different ordered structures. When alanine linkers are introduced to these molecules between the core and the monosacchride, morphologies of three types of monosaccharide BTAs turned to disordered, meanwhile their structures become similar with the increase of the length of alanine linkers, indicating the disappearance of the monosaccharide effects.

关 键 词：MONOSACCHARIDE SELF-ASSEMBLY Benzenetricarboxamide DYNAMIC LIGHT scatting (DLS) Depolarized DYNAMIC LIGHT scatting (DDLS) 

分 类 号：O6[理学—化学]