石笋有机质碳同位素组成研究的进展与挑战  

Progress and challenge of organic carbon isotope composition research in stalagmite

作　　者：薛刚 蔡演军[1,3] 程鹏[1,4] 马乐 成星[1,2] XUE Gang;CAI Yanjun;CHENG Peng;MA Le;CHENG Xing(State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,Chinese Academy of Sciences,Xi’an 710061,China;University of Chinese Academy of Sciences,Beijing 100049,China;Institute of Global Environmental Change,Xi’an Jiaotong University,Xi’an 710054,China;Xi’an Accelerator Mass Spectrometry Center,Xi’an 710061,China)

机构地区：[1]中国科学院地球环境研究所黄土与第四纪地质国家重点实验室,西安710061 [2]中国科学院大学,北京100049 [3]西安交通大学全球环境变化研究院,西安710054 [4]西安加速器质谱中心,西安710061

出　　处：《地球环境学报》2019年第2期105-115,共11页Journal of Earth Environment

基　　金：国家重点研发计划(2017YFA0603401);黄土与第四纪地质国家重点实验室重大研究项目;黄土与第四纪地质国家重点实验室开放基金(SKLLQG1723)~~

摘　　要：洞穴石笋因其精准的定年和蕴含的多种代用指标,已成为古气候和古环境变化研究的重要载体之一。在石笋研究的多种代用指标中,碳酸盐碳同位素由于受到多重因素的影响,应用其重建过去环境变化历史一直局限在少数几个研究地点。洞穴上覆土壤有机质是洞穴石笋中有机质的重要来源,除此之外,洞穴原位产生的微生物及基岩中的有机质也有贡献。由于主要继承了地表植被和土壤有机质的同位素组成,石笋有机质碳同位素组成的时间序列能够很好地指示地表植被的演变及土壤过程的变化。本文对石笋有机质碳同位素组成的研究现状进行了综述,介绍了最新建立的石笋有机质碳同位素组成分析方法,并指出应用这一指标研究环境变化需要解决的关键问题和未来面临的挑战。Background, aim, and scope Speleothem has been one of the most important geological archives for reconstructing the paleoclimate and paleoenvironment because of multiple advantages, such as, absolute ages, high-resolution proxies. Many speleothem oxygen isotope composition sequences have been reconstructed by researchers around the world, they provided abundant scientific data for exploring local and global climate and environment change. However, the carbon isotope composition of carbonate has uncertainties to understand the changes of climate and environment due to the multiple affecting factors like the types and density of vegetation,soil process and vadose zone process or other environment factors, thus it only be applied to reconstruct past climate and environment change in few and specific study sites. Inversely, organic carbon isotope composition of stalagmite has significant potential and advantages that straight reflects the information of organic matter from overlying karst system. Although the organic carbon research still exists some problems on the source and content of organic matter, analytical technique and interpretations of organic proxies, yet there were two organic carbon isotope composition sequences have been published in recent years and provided practical and useful analytical technique. In this study, we reviewed and introduced the source of stalagmite organic matter, the advantages of organic matter proxies, and the development of analytical technique according to the published research, and we also proposed the key problems and future challenges on organic matter proxies research in speleothem. Materials and methods In this study, our stalagmite sample was collected from Xiaosumang Cave, Qinghai. We ground a portion of our study sample being the homogenized powder. The sub-samples were firstly and completely digested by phosphoric acid solution to remove the inorganic carbon. Once the digestion was complete, the residual solution and oxidant (50 mL super clean water + 2.0 g K2S2O8 + 10

关 键 词：石笋 有机质 碳同位素组成 环境变化 

分 类 号：P597[天文地球—地球化学]