氟草烟仲辛酯的合成研究  

Study on Synthesis of Fluroxypyr Meptyl

作　　者：何小强 李传武 林军 吴承丽 He Xiaoqiang;Li Chuanwu;Lin Jun;Wu Chengli(Chongqing Huage Biochemistry Limited Company,Chongqing 404000,China)

机构地区：[1]重庆华歌生物化学有限公司,重庆404000

出　　处：《化学世界》2019年第4期207-210,共4页Chemical World

摘　　要：研究了以五氯吡啶为原料,经氟化,氨基化,羟基化,缩合,共四步反应制得氟草烟仲辛酯,通过添加分子筛,缩短反应步骤,探究最佳反应条件。结果表明,采用A型分子筛,氨化反应温度为0～10℃,缩合温度为100～150℃,氟草烟仲辛酯的收率可达到73.5%。Synthesis of fluroxypyr meptyl through fluoridation, amination, hydroxylation and condensation with pentachloropyridine as starting material was studied. The synthetic steps were shortened by adding molecular sieve and the optimized reaction conditions were explored. The results show that when the molecular sieve is type-A, the temperature of fluoridation is 0~10 ℃ and the temperature of amination is 100~150 ℃, the yield of fluroxypyr meptyl was 73.5%.

关 键 词：氟草烟仲辛酯 五氯吡啶 分子筛 合成 

分 类 号：TQ457.2[化学工程—农药化工]