Effect of strain rate and crystalline inclusions on mechanical properties of bulk glassy and partially crystallized Zr_(52.5)Cu_(17.9)Ni_(14.6)Al_(10)Ti_5 alloy  

应变速率和晶体包裹体对大块非晶和部分结晶的Zr_(52.5)Cu_(17.9)Ni_(14.6)Al_(10)Ti_5合金力学性能的影响（英文）

作　　者：Tomasz KOZIE? Krzysztof PAJOR Grzegorz CIOS Piotr BA?A 

机构地区：[1]Faculty of Metals Engineering and Industrial Computer Science,AGH University of Science and Technology [2]Academic Centre for Materials and Nanotechnology,AGH University of Science and Technology

出　　处：《Transactions of Nonferrous Metals Society of China》2019年第5期1036-1045,共10页中国有色金属学报（英文版）

基　　金：supported by Ministry of Science and Higher Education Republic of Poland under contract No.11.11.110.299

摘　　要：The mechanical properties of the Zr52.5Cu17.9Ni14.6Al10Ti5 alloy were presented, with an emphasis on the strain rate effect and presence of crystalline inclusions on the deformation and fracture mechanisms. X-ray diffraction studies indicated fully amorphous alloy structures with lower oxygen contents and partial crystalline structures at higher oxygen levels;however, completely different compressive deformation behaviour was observed. Uniaxial compression tests of the fully amorphous alloy showed elastic deformation, followed by yielding, distinct plastic deformation and serration flow behaviour. An increase in strain rate from 1×10-4 to 1×10-2 s-1 did not affect the yield strength;however, it decreased the compressive fracture strength and reduced the plastic strain. Scanning electron microscopy (SEM) observations with energy dispersive spectroscopy (EDS) analysis showed that the intermetallic CuZr2 phase was present even in the low oxygen content alloy, leading to lower fracture strength and ductility loss. For the high oxygen level samples, the presence of the dendritic Zr51Cu28Al21 phase was confirmed, leading to fracture strength impairment. The difference between ductile and brittle samples has been reflected on the fracture surfaces. The higher the plastic strain was, the higher the density of shear bands forming during deformation manifested by a serration flow behaviour on stress-strain curves.研究Zr_(52.5)Cu_(17.9)Ni_(14.6)Al_(10)Ti_5合金的力学性能,着重研究应变速率和晶体包裹体对合金变形和断裂机制的影响。X射线衍射分析表明,低氧含量时形成完全非晶态的合金组织,而当氧含量较高时,形成部分晶化组织;但是观察到完全不同的压缩变形行为。单轴压缩试验表明,全非晶合金具有弹性变形、屈服、明显塑性变形和锯齿流变行为。当应变速率从1×10^(-4) s^(-1)增加到1×10^(-2) s^(-1)时,屈服强度没有变化,然而,压缩断裂强度和塑性应力均降低。扫描电镜(SEM)和能谱(EDS)分析表明,即使在低氧含量的合金中,依然存在金属间化合物相CuZr_2,从而降低了合金的断裂强度和韧性。结果还证实在高氧含量的样品中存在枝晶状的Zr_(51)Cu_(28)Al_(21)相,会进一步降低其断裂强度。在断口表面可观察到韧性试样和脆性试样之间的差异。塑性应变越大,变形过程中形成的剪切带的密度越高,表现为应力-应变曲线上的锯齿流变行为。

关 键 词：bulk metallic glasses compression test shear band X-ray diffraction 

分 类 号：TG139.8[一般工业技术—材料科学与工程]