Evaluation on Fabrication and Properties of Composite Polyurethane Coatings with Wollastonite Partially Substituting for Rutile Titanium Dioxide  

Evaluation on Fabrication and Properties of Composite Polyurethane Coatings with Wollastonite Partially Substituting for Rutile Titanium Dioxide

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作  者:Xiaojing Wang Wei Zhang Yangyang Yan Jing Wang Xiyao Wang 

机构地区:[1]School of Chemical Engineering and Technology , Tianjin University [2]School of Environmental Science and Engineering , Tianjin University

出  处:《Transactions of Tianjin University》2019年第3期293-300,共8页天津大学学报(英文版)

摘  要:This study aims to prepare a composite polyurethane coating through a facile synthesis process. Titanium dioxide, which is a component of the prepared hydroxyl acrylic resin polyurethane varnish, was partially substituted by wollastonite, and an optimal substitution ratio was obtained. Analyses based on scanning electron microscope, powder X-ray diffraction, and Raman scattering measurements demonstrated that the addition of wollastonite caused nearly no change in the basic structure of the coating. Coating with a substitution ratio of 25% showed high thermal stability, good cover effect, considerable moisture-proof and water resistance ability, great acidic and basic resistance, and improved performance and hardness in performance tests. Furthermore, the production cost was reduced significantly at this substitution ratio.This study aims to prepare a composite polyurethane coating through a facile synthesis process. Titanium dioxide, which is a component of the prepared hydroxyl acrylic resin polyurethane varnish, was partially substituted by wollastonite, and an optimal substitution ratio was obtained. Analyses based on scanning electron microscope, powder X-ray diffraction, and Raman scattering measurements demonstrated that the addition of wollastonite caused nearly no change in the basic structure of the coating. Coating with a substitution ratio of 25% showed high thermal stability, good cover effect, considerable moisture-proof and water resistance ability, great acidic and basic resistance, and improved performance and hardness in performance tests. Furthermore, the production cost was reduced significantly at this substitution ratio.

关 键 词:POLYURETHANE coating WOLLASTONITE RUTILE titanium dioxide HYDROXYL ACRYLIC acid Thermal stability 

分 类 号:T[一般工业技术]

 

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