基于半刚性双(噻唑基苯并咪唑)和不同羧酸的五个一维配合物的合成和表征（英文）  

Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers

作　　者：刘露 靳平宁 李英[1] 娄慧慧[1] 王键吉[3] 张裕平[1] 侯红卫[4] 杜锦阁 LIU Lu;JIN Ping-Ning;LI Ying;LOU Hui-Hui;WANG Jian-Ji;ZHANG Yu-Ping;HOU Hong-Wei;DU Jin-Ge(School of Chemistry and Chemical Engineering,Henan Institute of Science and Technology,Xinxiang,Henan 453003,China;Xinxiang Medical University,Xinxiang,Henan 453000,China;School of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang,Henan 453007,China;College of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450052,China;Department of Chemistry,Sanquan College of Xinxiang Medical University,Xinxiang,Henan 453003,China)

机构地区：[1]河南科技学院化学化工学院,新乡453003 [2]新乡医学院,新乡453003 [3]河南师范大学化学化工学院,新乡453007 [4]郑州大学化学与分子工程学院,郑州450052 [5]新乡医学院三全学院,新乡453003

出　　处：《无机化学学报》2019年第6期1076-1084,共9页Chinese Journal of Inorganic Chemistry

基　　金：河南科技学院高层次人才科研启动项目;河南师范大学博士后科研项目;河南省博士后科研项目;河南省高等学校重点科研项目(No.16A150007);河南省高等学校重点科研项目(No.16A150060);河南科技学院标志性创新工程项目(No.2015BZ02)资助

摘　　要：通过水热或溶剂热合成的方法制备了5个一维配合物{[Zn(btbb)0.5(m-phda)]·0.5H2O}n(1),{[Cd2(btbb)(adtda)2(H2O)]·H2O}n(2),[Mn2(btbb)(tbi)2]n(3),{[Cd(btbb)0.5(3-Nitro-o-bdc)(H2O)]·H2O}n(4)和[Cd2(btbb)(tbi)2]n(5)(btbb=1,4-双(2-(4-噻唑基)苯并咪唑-1-基甲基)苯,m-H2phda=间苯二甲酸,H2adtda=1,3-金刚烷二羧酸,H2tbi=5-叔丁基间苯二甲酸,3-Nitro-o-H2bdc=3-硝基-1,2-苯二甲酸)。配合物1是一个包含22元环的一维链。配合物2是一个包含8元环的一维链,并且氮配体在这个一维链中仅仅起到装饰作用。配合物3是一个一维双链结构。配合物4是一个包含14元环的一维链。配合物5是一个阶梯状的一维双链结构。Five coordination complexes,formulated as {[Zn(btbb)0.5(m-phda)]·0.5H2O}n (1),{[Cd2(btbb)(adtda)2(H2O)]·H2O}n (2),[Mn2(btbb)(tbi)2]n (3),{[Cd(btbb)0.5(3-Nitro-o-bdc)(H2O)]·H2O}n (4) and [Cd2(btbb)(tbi)2]n (5)(btbb=1,4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene,m-H2phda=m-phenylenediacetic acid,H2adtda=1,3-adaman-tanedicarboxylic acid,H2tbi=5-tert-butylisophthalic acid,3-Nitro-o-H2bdc=3-Nitro-1,2-benzenedicarboxylic acid),have been obtained by hydro(solv)thermal reactions and structurally characterized.Complex 1 exhibits a 1D chain structure containing 22-membered rings.Complex 2 features a 1D chain structure having an 8-membered rings and btbb serves only as an ornament here.Complex 3 is a 1D double chain structure.Complex 4 possesses a 1D chain structure containing 14-membered rings.Complex 5 shows a 1D double chain taking on stair-step.CCDC:1883643,1;1883644,2;1883645,3;1883646,4;1883647,5.

关 键 词：配合物 半刚性配体 羧酸 晶体结构 

分 类 号：O614.241[理学—无机化学] O614.242[理学—化学]