Sn-Beta沸石合成研究进展  

Advances in the synthesis of Sn-Beta zeolite

作　　者：蔡静 吴志杰[1] Cai Jing;Wu Zhijie(CNPC Key Laboratory of Catalysis,State Key Laboratory of Heavy Oil Processing,ChinaUniversity of Petroleum,Beijing 102249,China)

机构地区：[1]中国石油大学(北京)重质油国家重点实验室CNPC催化重点实验室

出　　处：《工业催化》2019年第6期1-8,共8页Industrial Catalysis

基　　金：国家自然科学基金(U1662131)资助项目

摘　　要：含强L酸中心的Sn-Beta沸石在生物质平台化合物转化中表现出独特的活性和选择性,具有广阔的应用前景。Sn-Beta沸石主要合成方法有干胶法、水热法和同晶取代法。不同方法制备的Sn-Beta沸石Sn活性位的微环境及酸性质存在差异,在反应中表现出不同的反应性能。主要介绍Sn-Beta沸石合成方法及控制合成的影响因素。Sn-Beta zeolite with strong Lewis acid site exhibits unique activity and selectivity in conversion of biomass derived platform compounds,and shows a bright prospect.Dry gel conversion method, hydrothermal synthesis method and isomorphous substitution method are the typical synthetic methods for Sn-Beta zeolite.The microenvironment of Sn active sites and the corresponding acidic properties of Sn-Beta zeolites from above methods are different, leading to different catalytic performance.Here, advances in synthetic methods for Sn-Beta zeolite and control factors of synthesis were introduced.

关 键 词：催化化学 Sn-Beta沸石 水热合成法 同晶取代法 干胶法 

分 类 号：TQ424.25[化学工程] O643.36[理学—物理化学]