通过电化学脱氢N—N偶联合成四取代肼化合物（英文）  

Electrochemical Synthesis of Tetrasubstituted Hydrazines by Dehydrogenative N—N Bond Formation

作　　者：冯恩祺 侯中伟 徐海超 Feng Enqi;Hou Zhongwei;Xu Haichao(College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005)

机构地区：[1]厦门大学化学化工学院

出　　处：《有机化学》2019年第5期1424-1428,共5页Chinese Journal of Organic Chemistry

基　　金：Project supported by the National Natural Science Foundation of China(No.21672178);the National Foundation for Fostering Talents in Basic Science(No.J1310024)~~

摘　　要：通过电氧化二级芳胺合成了一系列四取代肼化合物.该电合成反应采用简单的装置如单室电解槽和恒电流电解,且无需过渡金属催化剂和氧化试剂,并可放大至克级规模.An electrochemical synthesis of tetrasubstituted hydrazines through dehydrogenative dimerization of secondary amines has been developed. The reactions are conducted in a simple undivided cell with constant current. The use of electricity to promote the reactions obviates the need for transition metal catalysts and oxidizing reagents, providing an efficient and sustainable access to tetrasubstituted hydrazines with diverse electronic properties.

关 键 词：有机电合成 电氧化 脱氢偶联 四取代肼 

分 类 号：O621.25[理学—有机化学]