1-氯甲基萘的绿色合成  

Green Synthesis of 1-Chloromethylnaphthalene

作　　者：范凯 刘连鹏 仝其祥 刘治 刘允攀 孙庆东 FAN Kai;LIU Lianpeng;TONG Qixiang;LIU Zhi;LIU Yunpan;SUN Qingdong(Pugang Binder Chemistry Co.Ltd,Puyang 457000,China)

机构地区：[1]濮阳班德路化学有限公司,河南濮阳457000

出　　处：《河南化工》2019年第6期16-18,共3页Henan Chemical Industry

摘　　要：采用氯化锌为催化剂成功合成了1-氯甲基萘,液相色谱检测显示1-氯甲基萘的纯度达到99.1%,副产物2-氯甲基萘的含量仅为0.3%。该法条件温和,三废减少,符合绿色化学发展观念。Using zinc chloride as a catalyst,1-Chloromethylnaphthalene is successfully synthesized.The liquid chromatographic monitoring showes that the purity of 1-chloromethylnaphthalene reaches 99.1%,and the content of by-product 2-chloromethylnaphthalene is only 0.3%.The conditions of this method are mild,the three wastes are reduced,consistent with the concept of green chemical development.

关 键 词：布兰克氯甲基化反应 氯化锌 1-氯甲基萘 

分 类 号：TQ23[化学工程—有机化工]