侧链PEG基聚合物的制备及其催化酯化反应性能  

Preparation of Side Chain PEG Based Polymer and Its Catalytic Performance for Esterification

作　　者：王泽溟 李旻昊 周宏勇[1] 王家喜[1,2] Wang Zeming;Li Minhao;Zhou Hongyong;Wang Jiaxi(School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130;Hebei Provincial Key Lab of Green Chemical Technology and High Efficient EnergySaving,Hebei University of Technology,Tianjin 300130)

机构地区：[1]河北工业大学化工学院,天津300130 [2]河北省绿色化工与高效节能实验室,天津300130

出　　处：《化学通报》2019年第6期542-548,482,共8页Chemistry

摘　　要：聚乙二醇单(乙烯基苄基)醚(PEG-VBE)和聚乙二醇二(乙烯基苄基)醚(PEG-DVBE)是重要的可聚合聚乙二醇衍生物,可用于催化剂载体及功能高分子的合成。本文以氢氧化钾为碱,乙烯基苄基氯(VBC)与乙二醇、一缩二乙二醇、二缩三乙二醇、PEG400、PEG600和PEG1500反应,高效合成了一系列乙烯基苄基聚乙二醇衍生物,乙烯基苄基氯的转化率可达96%以上,PEG-VBE的分离收率为32%~93%。乙烯基衍生物在过硫酸钾引发下聚合得到水溶性高分子,产物经1H NMR、ESI-HRMS及FT-IR分析表征。以制备的水溶性PEG基聚合物为微反应器,研究了苯甲酸与甲醇的酯化反应,在优化的条件下,苯甲酸的转化率可达99%以上,催化体系循环5次后,催化活性几乎没有下降。Polyethylene glycol vinylbenzyl ether(PEG-VBE)and polyethylene glycol di(vinylbenzyl)ether(PEG-DVBE)are important polymerizable PEG-derivatives,which have good applications in the fields of catalyst support and functional polymers.In this paper,a series of PEG-VBE and PEG-DVBE were prepared by reaction of vinyl benzyl chloride(VBC)with ethylene glycol,diethylene glycol,triethylene glycol,PEG400,PEG600,and PEG1500 using KOH as base.The conversion rate of VBC is more than 96%,and the separation yield of PEG-VBE is in range of 32%~93%.The products were characterized by 1H NMR、ESI-HRMS and FT-IR.Using PEG based polymer as microreactor,the esterification of benzoic acid and methanol was investigated.The combination of PEG based polymer with sulfuric acid has very good catalytic activity on the esterification.At the optimized condition,the conversion of benzoic acid is up to 99%.The catalytic activity is barely decreased after five cycles.

关 键 词：聚乙二醇 乙烯基苄基氯 醚化 微乳液 酯化 

分 类 号：O643.36[理学—物理化学] O621.251[理学—化学]