鲍林的化学键理论的思想起源  

Intellectual Origins of the Chemical Bond Theory of Linus Pauling

作　　者：陈功东 Chen Gongdong(School of Humanities,University of Chinese Academy of Sciences,Beijing 100049;College of Ethaology and Sociology,Guangxi University for Nationalities,Nanning 530006)

机构地区：[1]中国科学院大学人文学院 [2]广西民族大学民族学与社会学学院

出　　处：《化学通报》2019年第6期566-575,515,共11页Chemistry

基　　金：国家留学基金委建设高水平大学公派留学项目资助

摘　　要：化学键是化学与物理学于20世纪早期产生交融的重要问题,其中以美国化学家鲍林在30年代提出的价键理论最有影响力。该理论同时具有化学和物理学的多个思想来源,从19世纪后期的经典结构化学直到当时刚诞生的量子力学,以及路易斯化学键理论、X射线晶体学和物理化学。物理学比化学的影响更广,但两种来源都注重实验,演化历程中理论向实验靠拢的程度更大。Chemistry and physics interacted considerably on the problem of chemical bond during the early twentieth century.Among them,the influence of the theory put forward by American chemist Pauling in the early 1930s is the most significant.Pauling’s work had several origins from both chemistry and physics,ranging from classical structural chemistry in late nineteenth century to quantum mechanics just articulated then,and those training him directly including the chemical bond theory of Lewis,X-ray crystallography,and physical chemistry.Physical origins have more prominent influence than chemical,while both sorts regard experiment,and theoretical aspects show more convergence to the empirical than the reverse.

关 键 词：化学键 鲍林 价键理论 晶体结构 量子力学 理论与实验 

分 类 号：O641.1[理学—物理化学]