同质界面浓度对P型Bi0.5Sb1.5Te3合金热电性能的影响  

Effects of Homogeneous Interface Density on Thermoelectric Performance of P-type Bi0.5Sb1.5Te3 Alloy

作　　者：孙超 王小宇[1] 徐亮[1] 许飞 孙志豪 朱彬[1] 祖方遒[1] SUN Chao;WANG Xiao-yu;XU Liang;XU Fei;SUN Zhi-hao;ZHU Bin;ZU Fang-qiu(Liquid/Solid Metal Processing Institute,School of Materials Science & Engineering,Hefei University of Technology, Hefei 230009,China)

机构地区：[1]合肥工业大学材料科学与工程学院液/固金属加工研究所

出　　处：《稀有金属与硬质合金》2019年第3期47-50,共4页Rare Metals and Cemented Carbides

基　　金：国家自然科学基金(51371073);安徽省自然科学基金(1808085ME108)

摘　　要：界面对材料的电声输运性能具有明显的调控作用。基于此,探究了同质界面浓度对P型Bi0.5Sb1.5Te3合金热电性能的影响。结果表明:随着同质界面浓度的增大,材料的电导率降低,Seebeck系数增大;界面浓度增加强化了对声子的散射,故热导率降低;经1min粉碎的烧结样品具有更优的高温电学性能,故其高温端热电性能更优。The interface has a significant regulatory effect on the electroacoustic transport properties of the material.Therefore,the effect of homogeneous interface density on thermoelectric performance of P-type Bi0.5 Sb1.5Te3 alloy was investigated. The results show that the electrical conductivity of the alloy decreases and Seebeck coefficient increases with the increase of homogeneous interface density. Meanwhile,the ther mal conductivity decreases attributed to the enhanced scattering of phonons by increasing homogeneous in terface density. Because the sintered sample prepared by pulverizing for 1 min has the optimal electrical properties,it has excellent thermoelectric performance in the high temperature range.

关 键 词：P型Bi0.5Sb1.5Te3 同质界面浓度 热电性能 机械粉碎 

分 类 号：TB34[一般工业技术—材料科学与工程]