星天牛聚集信息素合成研究  

Synthesis of Aggregation Pheromone of Anoplophora Chinensis

作　　者：陆军 吴志民 刘辉 LU Jun;WU Zhi-min;LIU Hui(Suzhou Huadao Biological Pharmacy Co.,Ltd.,Jiangsu Suzhou 215008,China)

机构地区：[1]苏州华道生物药业股份有限公司,江苏苏州215008

出　　处：《广州化工》2019年第12期51-52,共2页GuangZhou Chemical Industry

摘　　要：以价廉易得的四氢呋喃和1-庚醇为起始原料,分别经过开环反应、保护反应、取代反应、去保护反应和氧化反应,合成了星天牛聚集信息素4-(正庚氧基)-1-丁醇和4-(正庚氧基)-1-丁醛,二者的总收率分别为47%和41%;产物结构利用核磁共振氢谱进行了表征,产品的纯度利用气相色谱仪进行检测。本工艺原料易得,反应条件温和可控,无安全隐患,易于操作,适合放大生产。The aggregation pheromone of anoplophora chinensis,4-(n-heptyloxy )butan-1-ol and 4-heptyloxy-butyraldehyde,were syhthesized from tetrahydrofuran and 1-heptanol as the the starting materials by the ring opening reaction,protection reaction,nucleophilic substitution reaction,deprotection reaction and oxidation reaction,the overall yields of the products were 47% and 41%,and the products were charaterized by HNMR and GC. This method offered several advantages such as normal materials,simple experimental and scale-up procedures.

关 键 词：星天牛 聚集信息素 合成 4-(正庚氧基)-1-丁醇 4-(正庚氧基)-1-丁醛 

分 类 号：O624.1[理学—有机化学]