含邻位-碳硼烷与二茂铁基的新型半夹心式钌化合物的合成  

Synthesis of Novel Half-sandwich Ruthenium Compounds Containing ortho-Carborane and Ferrocenyl Units

作　　者：胡久荣 祝长鹏 叶明星 钟修鹏 张洪杰 林莹 HU Jiu-rong;ZHU Chang-peng;YE Ming-xing;ZHONG Xiu-peng;ZHANG Hong-jie;LIN Ying(School of Chemistry and Environmental Sciences,Shangrao Normal University,Shangrao 334001,China)

机构地区：[1]上饶师范学院化学与环境科学学院

出　　处：《合成化学》2019年第7期543-546,553,共5页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(21261020);江西省教育厅科技项目(GJJ170921);上饶师范学院科技项目(G201803);上饶师范学院大学生创新训练项目(2018-CX-28)

摘　　要：以邻位-碳硼烷、正丁基锂、硫粉和[(p-cymene)RuCl2]2为原料,参考文献方法制得化合物(p-cymene)Ru(S2C2B10H10)(1)和(p-cymene)Ru2(μ-S2)(S2C2B10H10)2(2)(p-cymene=对甲基异丙基苯基);HC≡CC(O)Fc(Fc=二茂铁基)分别与1和2反应合成了新化合物(p-cymene)Ru(S2C2B10H9)(H2C=CC(O)Fc)(3)和(p-cymene)Ru2(μ-S2)(S2C2B10H10)2(R^1C=CR^2)[R^1=FcCO,R^2=H(4);R^1=H,R^2=FcCO(5)],其结构经1HNMR,^13C NMR,^11B{^1H}NMR,IR,MALDI-TOF-MS和元素分析表征。Treatment of ortho -carborane, n -butyl lithium, sulfur and [( p -cymene)RuCl 2 ] 2 led to two compounds ( p -cymene)Ru(S 2 C 2 B 10 H 10 )( 1 ) and ( p -cymene)Ru 2 (μ-S 2 )(S 2 C 2 B 10 H 10 ) 2 ( 2 ) by reference method. The addition reactions of HC≡CC(O)Fc (Fc=ferrocenyl)with 1 and 2 afford to the new complexes ( p -cymene)Ru(S 2 C 2 B 10 H 9 )(H 2 C=CC(O)Fc)( 3 ) and ( p -cymene)Ru 2 (μ-S 2 )( S 2 C 2 B 10 H 10 ) 2 (R 1 C=CR 2 )[R^1=FcCO, R^2=H( 4 );R^1=H, R^2=FcCO( 5 )]. The structures were characterized by ^1 H NMR,^13 C NMR,^11 B{^1 H} NMR, IR, MALDI-TOF-MS and elemental analysis.

关 键 词：邻位-碳硼烷 二茂铁 金属钌化合物 合成 

分 类 号：O614.82[理学—无机化学]