棉短绒纤维素基复合材料的制备及吸油性能  

Preparation and Oil Absorption Properties of Cotton Linters Cellulose Matrix Composites

作　　者：冯晓宁 丁成立[1,2] 刘月娥[1,2] Xiaoning Feng;Chengli Ding;Yue’e Liu(School of Chemistry and Chemical Engineering,Xinjiang University;Key Laboratory of Coal Clean Conversion & Chemical EngineeringProcess of Xinjiang Uyghur Autonomous Region,Urumqi 830046,China)

机构地区：[1]新疆大学化学化工学院 [2]新疆大学化学化工学院煤炭清洁转换与化工过程自治区重点实验室,新疆乌鲁木齐830046

出　　处：《高分子材料科学与工程》2019年第7期25-30,共6页Polymer Materials Science & Engineering

基　　金：国家自然科学基金资助项目(21666035);新疆维吾尔自治区高校科研重点项目(XJEDU20161019)

摘　　要：以棉短绒为原料,硝酸铈铵/HNO3为引发剂,甲基丙烯酸缩水甘油酯(GMA)/苯乙烯(St)为单体,N′N-亚甲基双丙烯酰胺为交联剂,接枝共聚制备吸油材料。考察体系反应温度、反应时间、引发剂浓度和单体浓度对材料吸油倍率的影响,获得制备改性材料的最佳工艺,对所制备的材料进行红外光谱、热重分析和扫描电镜表征。结果表明,在引发剂浓度为0.06 mol/L,单体浓度为0.7 mol/L,反应温度为90℃,反应时间为18 h的条件下,得到的吸油材料最大吸油倍率可达19.4 g/g。吸油重复性测定表明,该吸油材料具有较好的重复使用性。Oil absorption materials were prepared via the graft copolymerization of cotton linte cellulose as raw material,ceric ammonium nitrate/HNO3 as initiator,glycidyl methacrylate(GMA)/styrene(St)as monomer and N'N-methylene bisacrylamide as cross-linkingagent.The effects of system reaction temperature,reaction time,initiator concentration and monomer concentration on the oil absorption ratio of the materials were investigated.The optimum process for preparing the modified materials was obtained and characterized by FT-IR,TG and SEM.The results show that when the initiator concentration is 0.06 mol/L and the monomer concentration is 0.7 mol/L at 90℃for 18 h,The maximum oil absorption rate of the oil absorbing material reaches 19.4 g/g.The oil absorption reusability measurement shows that the oil absorbing material has a good reuse performance.

关 键 词：棉短绒纤维素 甲基丙烯酸缩水甘油酯 苯乙烯 吸油材料 重复使用性 

分 类 号：TQ340.64[化学工程—化纤工业]