基于杯吡咯及其衍生物的化学传感器研究进展  

Research progress of chemical sensor based on calixpyrrole and its derivative

作　　者：张政 朱照琪[1] 孙寒雪[1] 魏慧娟[1] 李安 Zhang Zheng;Zhu Zhaoqi;Sun Hanxue;Wei Huijuan;Li An(College of Petrochemical Technology,Lanzhou University of Technology,Lanzhou 730050)

机构地区：[1]兰州理工大学石油化工学院

出　　处：《化工新型材料》2019年第7期5-8,共4页New Chemical Materials

基　　金：国家自然科学基金项目(51663012,51462021)

摘　　要：杯吡咯是近年来一类新兴的超分子主体化合物,由于其独特的结构和理化性质,使得杯吡咯及其衍生物在识别金属离子、阴离子和中性小分子方面应用广泛。通过引入不同基团、改变其空腔大小得到的主体可以与不同大小、不同性质的客体分子相匹配,可作为敏感材料应用于离子选择电极、离子敏感场效应管、压电晶体、离子光导膜等多种类型的化学传感器上,对各种阴离子和中性分子的识别和检测。Calixpyrrole was a new class of supramolecular host compounds in recent years.Because of its unique structure and physicochemical properties,calixpyrrole and its derivatives have been widely used in the recognition of metal ions,anions and neutral small molecules.By introducing different groups,the main body which can change the cavity size can match the guest molecules of different size and different nature,and can be used as the sensitive material in ion selective electrode,ion sensitive field effect transistor,piezoelectric crystal,ion photoconductive film And many other types of chemical sensors,for a variety of ions and neutral molecules identification and detection。

关 键 词：杯吡咯衍生物 阴离子检测 化学传感器 分子识别 

分 类 号：O641.3[理学—物理化学] TP212.2[理学—化学]