柔性基金属氧化物超级电容器电极材料的研究进展  

Research progress of flexible base metal oxide supercapacitor electrode materials

作　　者：黄继伟 钱学仁[1] 安显慧[1] 李响 HUANG Jiwei;QIAN Xueren;AN Xianhui;LI Xiang(Key Laboratory of Bio - based Material Science and Technology of Ministry of Education , College of Materials Science and Engineering , Northeast Forestry University , Harbin 150040 , China)

机构地区：[1]东北林业大学材料科学与工程学院生物质材料科学与技术教育部重点实验室

出　　处：《功能材料》2019年第8期8040-8050,共11页Journal of Functional Materials

基　　金：国家自然科学基金资助项目(31170552)

摘　　要：作为一种介于传统电容器和电池之间的新型电化学储能器件,超级电容器的整体性能主要受限于电极材料。研究发现,具有赝电容特性的过渡金属氧化物因其多重氧化态、多金属离子特性和高理论比容量,在电化学储能相关领域备受关注。首先简要阐述了柔性超级电容器的结构及储能机理。然后,概述了以不同元数的过渡金属氧化物为主体构筑的“二元”和“三元”柔性复合电极材料。接着,总结了由复合电极材料组装成的柔性超级电容器在可穿戴电子设备和多功能柔性器件--储能智能窗(ESS窗)方面的应用。最后,提出了过渡金属氧化物基柔性超级电容器在实际应用中所面临的挑战及今后的主要研究方向。As a new type of electrochemical energy storage device between a conventional capacitor and a battery , the overall performance of the supercapacitor was mainly limited by the electrode material.It is found that tran - sition metal oxides with pseudocapacitance property have attracted much attention in the field of electrochemical energy storage due to their multiple oxidation states , polymetallic ion characteristics and high theoretical specif - ic capacity.In this paper , the structure and energy storage mechanism of flexible supercapacitors were briefly described first.Then , the “ binary ” and “ ternary ” flexible composite electrode materials constructed with differ - ent numbers of transition metal oxides were summarized.Next , the application of the flexible supercapacitor as - sembled from the composite electrode materials in the wearable electronic device and the multifunctional flexible device , the energy storage smart window ( ESS window ), was summarized.Finally , the challenges faced by the transition metal oxide - based flexible supercapacitors in practical applications and the main research directions in the future were proposed.

关 键 词：超级电容器 电极材料 柔性基底 金属氧化物 

分 类 号：TB34[一般工业技术—材料科学与工程]