Thermal stability, crystallization, and magnetic properties of FeNiBCuNb alloys  

作　　者：Zhe Chen Qian-Ke Zhu Shu-Ling Zhang Ke-Wei Zhang Yong Jiang 陈哲;朱乾科;张树玲;张克维;姜勇(School of Materials Science and Engineering,Taiyuan University of Science and Technology,Taiyuan 030024,China;School of Material of Science and Engineering,North Minzu University,Yinchuan 750021,China)

机构地区：[1]School of Materials Science and Engineering,Taiyuan University of Science and Technology,Taiyuan 030024,China [2]School of Material of Science and Engineering,North Minzu University,Yinchuan 750021,China

出　　处：《Chinese Physics B》2019年第8期339-344,共6页中国物理B（英文版）

基　　金：Project supported by the National Natural Science Foundation of China(Grant No.51731003);the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi Province,China(2014);the “131” Leading Talents Project of Higher Education Institutions in Shanxi Province,China(2015);the Overseas Students Science and Technology Activities Project Merit Funding,China(2016);the Fund for Shanxi Key Subjects Construction

摘　　要：Amorphous(Fe40Ni40B19Cu1)100-xNbx(x=1,3,5,7)ribbons are prepared by using the melt-spinning method.We find that the glass forming ability(GFA)of the as-melt spun ribbons is significantly improved by adding Nb element.In addition,the thermal stability evaluated in steps of△T=Tx2-Tx1 effectively increases from 16 K to 75 K with Nb content increasing.The as-melt spun(Fe40Ni40B19Cu1)97 Nb3 ribbon exhibits a lowest coercivity of 2 A/m and relatively large saturation magnetization of 103.7 A·m^2/kg and thus it can be further treated by being annealed at 809 K.The crystallization behavior is confirmed to be determined by two individual crystallization processes corresponding to the precipitation of(Fe,Ni)23 B6 phase andγ-(Fe,Ni)phase.With increasing annealing time,the single(Fe,Ni)23B6 phase can be transformed into a mixture of(Fe,Ni)23B6 andγ-(Fe,Ni)phase,and the grain size ofγ-(Fe,Ni)phase increases from 5 nm to 80 nm while the grain size of(Fe,Ni)23B6 remains almost unchanged.Finally,we find that the grain growth in each of(Fe,Ni)23B6 andγ-(Fe,Ni)deteriorates the overall magnetic properties.Amorphous(Fe40Ni40B19Cu1)100-xNbx（x = 1, 3, 5, 7） ribbons are prepared by using the melt-spinning method. We find that the glass forming ability（GFA） of the as-melt spun ribbons is significantly improved by adding Nb element. In addition, the thermal stability evaluated in steps of ?T = Tx2-Tx1 effectively increases from 16 K to 75 K with Nb content increasing. The as-melt spun(Fe40Ni40B19Cu1)97 Nb3 ribbon exhibits a lowest coercivity of 2 A/m and relatively large saturation magnetization of 103.7 A·m2/kg and thus it can be further treated by being annealed at 809 K. The crystallization behavior is confirmed to be determined by two individual crystallization processes corresponding to the precipitation of（Fe,Ni）23 B6 phase and γ-（Fe,Ni） phase. With increasing annealing time, the single（Fe,Ni）23B6 phase can be transformed into a mixture of（Fe,Ni）23B6 and γ-（Fe,Ni） phase, and the grain size of γ-（Fe, Ni） phase increases from 5 nm to 80 nm while the grain size of（Fe,Ni）23B6 remains almost unchanged. Finally, we find that the grain growth in each of（Fe,Ni）23B6 and γ-（Fe, Ni） deteriorates the overall magnetic properties.

关 键 词：as-melt SPUN glass forming ability CRYSTALLIZATION COERCIVITY 

分 类 号：O4[理学—物理]