由吡啶-三羧酸配体构筑的锌(Ⅱ)和锰(Ⅱ)配合物的合成、晶体结构、荧光及磁性质（英文）  

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of One 0D Zinc(Ⅱ) and Two 1D Manganese(Ⅱ) Coordination Compounds Assembled from Pyridine-Tricarboxylate Blocks

作　　者：黎彧[1] 潘光敏 邹训重 冯安生[1] 游遨[1] 邱文达[1] LI Yu;PAN Guang-Min;ZOU Xun-Zhong;FENG An-Sheng;YOU Ao;QIU Wen-Da(Guangdong Research Center for Special Building Materials and Its Green Preparation Technology /Foshan Research Center for Special Functional Building Materials and Its Green PreparationTechnology,Guangdong Industry Polytechnic,Guangzhou 510300,China;School of Chemical Engineering and Light Industry,Guangdong University of Techlonogy,Guangzhou 510006,China)

机构地区：[1]广东轻工职业技术学院,广东省特种建筑材料及其绿色制备工程技术研究中心/佛山市特种功能性建筑材料及其绿色制备技术工程中心,广州510300 [2]广东工业大学轻工化工学院,广州510006

出　　处：《无机化学学报》2019年第10期1853-1860,共8页Chinese Journal of Inorganic Chemistry

基　　金：广东省高等职业院校珠江学者岗位计划资助项目(2015,2018);广东省自然科学基金(No.2016A030313761);广东轻院珠江学者人才类项目(No.RC2015-001);广东轻院科技成果培育项目(No.KJPY2018-010);广东轻院优秀青年基金(No.QN2018-007);生物无机与合成化学教育部重点实验室开放基金(2016);广东省高校创新团队项目(No.2017GKCXTD001);广州市科技计划项目(No.201904010381);广东大学生科技创新培育专项(No.pdjh2019b0690)资助

摘　　要：采用水热方法,用吡啶-三羧酸配体(H3L)和2,2′-联咪唑(H2biim 2,2′-biimidazole)、菲咯啉(phen)、2,2′-联吡啶(2,2′-bipy)分别与ZnCl2和MnCl2·4H2O反应,合成了1个零维配合物[Zn(H2biim)2(H2O)2][Zn(HL)(Hbiim)(H2O)]2·8H2O(1)和2个具有一维链结构的配合物[Mn(μ-HL)(phen)(H2O)]n(2)、{[Mn(μ-HL)(2,2′-bipy)(H2O)]·0.5(2,2′-bipy)}n(3),并对其结构、荧光和磁性质进行了研究。结构分析结果表明3个配合物分别属于单斜晶系的P21/n和P21/c空间群。配合物1具有3个单核Zn单元组成的零维结构,这些单核单元通过O-H…O/N和N-H…O氢键作用进一步形成了三维超分子框架。配合物2和3具有一维链结构,而且这些链通过O-H…O氢键作用进一步形成了二维超分子网络。研究表明,配合物1在室温下能发出蓝色荧光,聚合物2中相邻Mn?髤离子间存在反铁磁相互作用。One 0D zinic(Ⅱ)and two 1D manganese(Ⅱ)coordination compounds,namely[Zn(H2biim)2(H2O)2][Zn(HL)(Hbiim)(H2O)]2·8H2O(1),[Mn(μ-HL)(phen)(H2O)]n(2)and{[Mn(μ-HL)(2,2′-bipy)(H2O)]·0.5(2,2′-bipy)}n(3)have been constructed hydrothermally using H3L(H3L=4-(6-carboxy-pyridin-3-yl)-isophthalic acid),H2biim(H2biim=2,2′-biimidazole),phen(phen=1,10-phenanthroline),2,2′-bipy(2,2′-bipy=2,2′-bipyridine),and zinc or manganese chlorides.Single-crystal X-ray diffraction analyses reveal that three compounds crystallize in the monoclinic system,space groups P21/n or P21/c.Compound 1 shows a 0D structure composed of three monomer Zn(Ⅱ)units,which is arranged into a 3D supramolecular framework through O-H…O/N or N-H…O hydrogen bonds.Compounds 2 and 3 feature a 1D metal-organic chain,which is assembled to a 2D supramolecular network through O-H…O hydrogen bond.The luminescent and magnetic properties for three compounds were also investigated.

关 键 词：配位聚合物 吡啶-三羧酸配体 荧光 磁性 

分 类 号：O614.241[理学—无机化学] O614.711[理学—化学]