序列可控N-取代马来酰亚胺类多元共聚物的研究进展  

Progress of Sequence-Controlled N-Substituted Maleimide Multi-Component Copolymers

作　　者：赵潜 刘玉飞[1,2] 何敏[1,2] 战奕凯 龚勇吉 李莉萍[1] 于杰[2] QianZhao;YufeiLiu;MinHe;YikaiZhan;YongjiGong;LipingLi;JieYu(College of Materials Science and Metallugry Engineering,Guizhou University,Guiyang 550025,China;National Engineering Research Center for Compounding and Modification of Polymeric Materials,Guiyang 550014,China)

机构地区：[1]贵州大学材料与冶金学院,贵州贵阳550025 [2]国家复合改性聚合物材料工程技术研究中心,贵州贵阳550014

出　　处：《高分子材料科学与工程》2019年第9期185-190,共6页Polymer Materials Science & Engineering

基　　金：国家自然科学基金资助项目(51663006);贵州省研究生科研基金(KYJJ2017012);贵州省教育厅自然科学研究项目(黔教合KY字[2015]359);贵州省科技计划项目(黔科合平台人才[2017]5788号)

摘　　要：序列可控N-取代马来酰亚胺类多元共聚物一直是高分子序列可控聚合领域的研究热点。文中立足当前国内外N-取代马来酰亚胺类多元共聚物序列可控聚合的研究现状,基于N-取代马来酰亚胺特殊的分子结构及其对应构-效关系,分类综述实现N-取代马来酰亚胺多元共聚物序列可控聚合的创新性策略,探究阐释合成机理,并对该领域潜在发展趋势及挑战进行展望,以期为从事聚合物分子序列精确设计的研究者提供普适性参考。Sequence-controlled N-substituted male-imide multi-component copolymers have always been a research hotspot in the field of the controlled polymerization of macromolecular sequences. This review focused on the current research status of the controllable polymerization of N-substituted male-imide multi-component copolymers from both domestic and overseas literature, based on the special molecular structure of N-substituted male-imide and its structure-property relationship, mainly summarized and interpreted the innovative strategies for achieving the controlled polymerization of N-substituted maleimide multi-component copolymers and the synthesis mechanism of the target products. The potential development trends and challenges of researches in this field were also foreseen in order to provide a universal reference for researchers working on the precise design of polymers.

关 键 词：N-取代马来酰亚胺 序列可控聚合 构效关系 合成机理 

分 类 号：TQ316.342[化学工程—高聚物工业]