杂环化合物C-H键活化研究进展  

Research Progress on C-H Bond Activation of Heterocyclic Compounds

作　　者：张亭妍 委旭宁 王宏雁[1] 刘钟栋[1] 魏国华 ZHANG Ting-yan;WEI Xu-ning;WANG Hong-yan;LIU Zhong-dong;WEI Guo-hua(Henan University of Technology,Henan Zhengzhou 450000;Yichun Big Turtle Life Science Co.,Ltd.,Jiangxi Yichun 336000,China)

机构地区：[1]河南工业大学,河南郑州450000 [2]宜春大海龟生命科学有限公司,江西宜春336000

出　　处：《广州化工》2019年第20期17-19,78,共4页GuangZhou Chemical Industry

摘　　要：杂环化合物是有机化学的重要组成部分,关于其C-H键的活化研究一直是有机工作者的关注热点,近年来大量关于杂环化合物C-H键活化实现C-C键的交叉偶联的文献被报道,其中包括金属钯催化、金属铜的催化、其他金属催化以及无金属催化等,杂环化合物广泛存在于自然界及活化分子中,在生物体内常常扮演着重要角色.综述了近年来该领域的研究进展,期望能对更多复杂有机杂环化合物的简便合成提供参考.Heterocyclic compounds are an important part of organic chemistry. The research on the activation of C-H bonds has been a hot topic of organic workers. In recent years, a large number of literatures on the cross-coupling of C- C bonds by the activation of heterocyclic compounds with C-H bonds have been reported, including metal palladium catalysis, metal copper catalysis, other metal catalysis and metal-free catalysis. Heterocyclic compounds are widely found in nature and activated molecules, and often play an important role in living organisms. Recent advances in this field were reviewed, hoping to provide a reference for the simple synthesis of more complex organic heterocyclic compounds.

关 键 词：杂环化合物 C-H键活化 金属催化 交叉偶联 

分 类 号：O626[理学—有机化学]