不同冷冻润滑油对HFO1234yf溶解吸收特性的研究  

Investigation of solubility behavior between HFO1234yf and lubricants

作　　者：孙艳军[1] 邸高雷 夏娟[2] 王晓坡[3] 龚娜[3] SUN Yanjun;DI Gaolei;XIA Juan;WANG Xiaopo;GONG Na(Institute of Building Energy & Sustainability Technology,School of Human Settlements and Civil Engineering,Xi’an Jiaotong University,Xi’an 710049,Shaanxi,China;China National Heavy Machinery Research Institute Co.,Ltd.,Xi’an 710032,Shaanxi,China;Key Laboratory of Thermo-Fluid Science and Engineering,Ministry of Education,Xi’an Jiaotong University,Xi’an 710049,Shaanxi,China)

机构地区：[1]西安交通大学人居环境与建筑工程学院,建筑环境与可持续技术研究所,陕西西安710049 [2]中国重型机械研究院股份公司,陕西西安710032 [3]西安交通大学热流科学与工程教育部重点实验室,陕西西安710049

出　　处：《化工学报》2019年第A02期25-30,共6页CIESC Journal

基　　金：国家自然科学基金项目(51606148)

摘　　要：在原有的溶解度实验台位基础上,研制了一套基于可视等体积饱和法的制冷剂/润滑油溶解实验系统,增加可视窗口的实验本体、调整恒温系统以及改进搅拌系统。采用新研制的实验系统,实验研究了温度范围为283.15~348.15K制冷剂HFO1234yf与角鲨烷的溶解吸收特性,并采用PR状态方程和HVOS混合规则及活度系数NRTL模型对实验结果进行了关联,计算值和实验值的平均相对误差为1.22%。此外,温度范围为283.15~323.15K内发现了不互溶分层的现象。On the basis of the original solubility experimental system, a new experimental system using the visual isochoric method was developed to measure the solubility for a refrigerant and a lubricant. In new experimental system, visual experimental cell was added, thermostatic system was adjusted, and magnetic stirring system was modified. Solubilities of HFO1234yf in squalane was measured between 283.15 K and 348.15 K. The experimental data were correlated by PR equation of state with HVOS mixing rule in which the excess Gibbs free energy was represented by the NRTL equation. The absolute average deviation between experimental and calculated data was 1.22 %. Moreover, the immiscibility between HFO134yf and squalane was found from 283.15 K to 323.15 K.

关 键 词：溶解性 状态方程 测量 相平衡 

分 类 号：TK121[动力工程及工程热物理—工程热物理]