杯[4]芳烃四丁醚的选择性硝化  

Selective Nitration of Calix[4]arene Tetraethers

作　　者：杨发福[1] 余天祥[2] 杨先金[2] 林深[1] 

机构地区：[1]福建师范大学化学系,福州350007 [2]武汉大学化学系

出　　处：《应用化学》2002年第11期1112-1114,共3页Chinese Journal of Applied Chemistry

基　　金：福建省青年科技人才创新资金 (2 0 0 1J0 2 5 );福建省省基金资助项目

摘　　要：mono-Nitro-, 1,3-bis-nitro-, tetra-nitro- and 1,2-bis-nitro-calixarenes were obtained separately by treating calixarene tetraethers with 65% HNO3 and HOAc in the yields of 70%, 62%, 15% and 50%, respectively. The reaction mechanism has been discussed.mono-Nitro-, 1,3-bis-nitro-, tetra-nitro- and 1,2-bis-nitro-calixarenes were obtained separately by treating calixarene tetraethers with 65% HNO_3 and HOAc in the yields of 70%, 62%, 15% and 50%, respectively. The reaction mechanism has been discussed.

关 键 词：芳烃四丁醚 选择性 硝化反应 1 芳烃 

分 类 号：O625.61[理学—有机化学]