茂型稀土金属有机配合物催化甲基丙烯酸酯类聚合研究进展  

Research Development of the Catalytic Activity to Methacrylates Polymerization of Rare Earth Organometallic Complexes Involving Cyclopentadienyl Types

作　　者：罗梅[1] 苏庆德[1] 马怀柱[2] 

机构地区：[1]中国科技大学化学系,中国安徽合肥230026 [2]安徽师范大学有机化学研究所,中国安徽芜湖241000

出　　处：《Chinese Journal of Structural Chemistry》2002年第6期583-591,共9页结构化学（英文）

摘　　要：综述了茂型稀土金属有机配合物催化甲基丙烯酸酯类聚合的研究现状和最新进展。系统地介绍了不同的茂型稀土金属有机催化体系中温度、反应时间、溶剂等条件对催化甲基丙烯酸酯类聚合的影响规律,并研究其催化反应机理,最后展望茂型稀土金属有机化学今后的研究方向及前景。The recent advance of the catalytic activity to methacrylates polymerization (PMAA) of rare earth organometallic complexes involving cyclopentadienyl types is reviewed. The effects of the temperature, solvent, reaction time and other factors to polymerization in different catalytic systems involving cyclopentadienyl types are systematically summarized and the catalytic mechanism is also discussed. Finally, prospects of the rare earth organometallic chemistry involving cyclopentadienyl types in the future are described.

关 键 词：研究进展 茂型稀土金属有机配合物 甲基丙烯酸酯类 聚合 催化剂 

分 类 号：TQ316.3[化学工程—高聚物工业]