新型高吸水聚合物凝胶型屏蔽暂堵剂MTC-1的合成及性能  

Synthesis and Properties of A Novel Super-absorbent Polymer Gel Type Shielding Temporary Blocking Agent MTC-1

作　　者：林海 韩亮 王文 霍锦华 LIN Hai;HAN Liang;WANG Wen;HUO Jin-hua(State Key Laboratory Offshore Oil Exploitation,Tianjin Branch,CNOOC China Ltd.,Tianjin 300459,China;College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu 610500,China)

机构地区：[1]中海石油有限公司天津分公司海洋石油高效开发国家重点实验室,天津300459 [2]西南石油大学化学化工学院,四川成都610500

出　　处：《合成化学》2019年第8期648-652,共5页Chinese Journal of Synthetic Chemistry

基　　金：中海油攻关课题“动态复杂压力体系下提升固井质量的水泥浆优化工艺及评价技术研究”(CCL2018TJTSWST0378)

摘　　要：以丙烯酸(AA)、丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为原料,蒙脱土(MMT)为改性剂,过硫酸钾和无水亚硫酸氢钠为氧化还原引发体系,六亚甲基四胺(C 6 H 12 N 4)为交联剂,采用水溶液聚合法合成了一种新型高吸水聚合物凝胶型屏蔽暂堵剂(MTC-1),其结构经IR表征。在最优合成条件(AM/AMPS/AA=11/7/1,m/m/m,引发剂加量0.6 wt%,于45℃反应2.5 h)下,MTC-1的最大吸水倍率为1006倍。岩心流动实验结果表明:MTC-1的堵水性能较高,封堵效率达到83.72%。A novel super-absorbent polymer gel type shielding temporary blocking agent(MTC-1)was synthesized by aqueous solution polymerization using AA,AM and AMPS as materials,MMT as modification agent,K 2 S 2 O 8 and NaHSO 3 as initiators,C 6 H 12 N 4 as crosslinker.The structure was characterized by IR.Under the optimal synthetic conditions(AM/AMPS/AA=11/7/1,m/m/m,initiators 0.6 wt%,reaction at 45℃for 2.5 h),the maximum water absorption ratio is 1006 times.Core flow experiment showed that MTC-1 exhibited well water shutoff performance with plugging ratio of 83.72%.

关 键 词：聚合物凝胶 屏蔽暂堵剂 水溶液聚合 合成 吸水倍率 堵水性能 

分 类 号：TQ314.2[化学工程—高聚物工业] O63[理学—高分子化学]