Recent advances on iron-catalyzed coupling reactions involving organolithium reagents  

作　　者：Zhuliang Zhong Xiao-Shui Peng Henry N.C.Wong 

机构地区：[1]Department of Chemistry, and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong

出　　处：《Chinese Chemical Letters》2019年第8期1463-1467,共5页中国化学快报（英文版）

基　　金：financed by National Natural Science Foundation of China (Nos. 21672181, 21272199);GRF/RGC (Nos. 403012, CUHK14309216, CUHK14303815);grant to the State Key Laboratory of Synthetic Chemistry from the Innovation and Technology Commission, The Chinese Academy of Sciences-Croucher Foundation Funding Scheme for Joint Laboratories;Direct Grant (No. 4053325) from The Chinese University of Hong Kong

摘　　要：Owing to their inexpensive and environmentally friendly properties,iron-based catalysts have been actively investigated for new organic reactions.In this account,we summarized our recent results on iron-catalyzed cross-coupling reactions and homo-coupling reactions.With iron-based catalysts,we constructed diverse carbon-carbon bonds,i.e.,C(sp^2)-C(sp^3),C(sp^3)-C(sp^3),C(sp^3)-C(sp^2)and C(sp^2)-C(sp^2)bonds.In order to demonstrate the usefulness of our iron protocol,we also carried out these reactions on gram-scale reactions,leading to good yields.Owing to their inexpensive and environmentally friendly properties, iron-based catalysts have been actively investigated for new organic reactions. In this account, we summarized our recent results on iron-catalyzed cross-coupling reactions and homo-coupling reactions. With iron-based catalysts, we constructed diverse carbon-carbon bonds, i.e., C(sp^2)-C(sp^3), C(sp^3)-C(sp^3), C(sp^3)-C(sp^2) and C(sp^2)-C(sp^2) bonds. In order to demonstrate the usefulness of our iron protocol, we also carried out these reactions on gram-scale reactions, leading to good yields

关 键 词：Iron-catalyzed CROSS-COUPLING HOMO-COUPLING ORGANOLITHIUM Gram-scale 

分 类 号：O64[理学—物理化学]