异丁烯选择性叠合技术研究开发进展  

ADVANCES IN ISOBUTYLENE SELECTIVE OLIGOMERIZATION PROCESS

作　　者：黄镇[1] 夏玥穜[1] 温朗友[1] 李佳琪 郜亮[1] 张伟[1] 宗保宁[1] Huang Zhen;Xia Yuetong;Wen Langyou;Li Jiaqi;Gao Liang;Zhang Wei;Zong Baoning(SINOPEC Research Institute of Petroleum Processing,Beijing 100083)

机构地区：[1]中国石化石油化工科学研究院

出　　处：《石油炼制与化工》2019年第9期108-115,共8页Petroleum Processing and Petrochemicals

基　　金：国家重点研发计划资助项目(2017YFB0306504)

摘　　要：介绍了异丁烯选择性叠合技术最新研究进展以及国外将MTBE装置改产异辛烯或异辛烷技术的成功经验,重点介绍中国石化石油化工科学研究院针对MTBE装置改造开发的选择性叠合技术。该技术工业试验结果表明,异丁烯转化率为90%~92%,C 8馏分选择性大于90%,产品RON为102~110,具备工业化条件。The latest research progresses in isobutylene selective oligomerization and the successful experience in revamping MTBE unit abroad to produce isooctane or isooctene are introduced,focusing on the technology developed by SINOPEC Research Institute of Petroleum Processing(RIPP)for isobutene selective oligomerization by revamping existing MTBE device.The industrial test results show that by RIPP`technology,the conversion rate of isobutylene is 90%-92%,the selectivity of C8 is more than 90%,and RON of the product is 102-110,indicating that it can be commercialized.

关 键 词：选择性叠合 异丁烯 异辛烯 MTBE 

分 类 号：TQ2[化学工程—有机化工]