纳米Fe-Al/Cr3C2复合涂层的抗电化学腐蚀性能  

Electrochemical corrosion resistance property of nano Fe-Al/Cr3C2 composite coating

作　　者：刘晓明[1,3] 马文 闫侯霞[4] 杨月红 韩吉伟 LIU Xiao-ming;MA Wen;YAN Hou-xia;YANG Yue-hong;HAN Ji-wei(Inner Mongolia Electric Power Research Institute,Hohhot 010020,China;School of Material Science and Technology,Inner Mongolia University of Technology,Hohhot 010020,China;Inner Mongolia Key Laboratory of Thin Film and Coatings,Hohhot 010051,China;Jinshan Thermal Power Co.,Ltd.of Inner Mongolia Energy Power Generation,Hohhot 010106,China)

机构地区：[1]内蒙古电力科学研究院,内蒙古呼和浩特010020 [2]内蒙古工业大学材料科学与工程学院,内蒙古呼和浩特010020 [3]内蒙古自治区薄膜与涂层重点实验室,内蒙古呼和浩特010051 [4]内蒙古能源发电金山热电有限公司,内蒙古呼和浩特010106

出　　处：《光学精密工程》2019年第9期1950-1959,共10页Optics and Precision Engineering

基　　金：内蒙古电力(集团)有限责任公司2019年第1批科技项目(No.201901097)

摘　　要：研究纳米Fe-Al/Cr 3C 2复合涂层的抗电化学腐蚀性能,确定纳米Fe-Al/Cr 3C 2团聚颗粒加入量的最佳值。采用三电极系统,对微米Fe-Al/Cr 3C复合涂层、纳米Fe-Al/Cr 3C 2和分别添加了5%,10%,15%纳米Fe-Al/Cr 3C 2团聚颗粒的系列复合涂层抗电化学腐蚀性能进行测试;利用Zview软件拟合交流阻抗谱,从定性到定量拟合对纳米Fe-Al/Cr 3C 2系列复合涂层的电化学腐蚀行为进行分析;利用扫描电子显微镜观察腐蚀后涂层表面形貌。添加了5%纳米Fe-Al/Cr 3C 2团聚颗粒的复合涂层自腐蚀电位为-0.775 V,自腐蚀电流为0.280 mA/cm 2,与其它涂层相比抗电化学腐蚀性能最优;此处添加的5%纳米级Fe-Al/Cr 3C 2团聚颗粒的复合涂层的特征主要以均匀腐蚀性为主,而其它Fe-Al/Cr 3C 2复合涂层都表现为一定的局部腐蚀特性。Fe-Al/Cr 3C 2复合涂层本身的抗电化学腐蚀特性会受到Fe-Al/Cr 3C 2团聚颗粒的影响而存在改善的价值。加入量低于最佳值时,涂层因表面质量没有得到改善而抗电化学腐蚀性能较低;加入量高于最佳值时,涂层因表面高活性而导致抗电化学腐蚀性能较低。The electrochemical corrosion resistance properties of nano Fe-Al/Cr 3C 2 composite coating were tested.The ideal amount of nano Fe-Al/Cr 3C 2 reunion-granulation particle to be added was determined.Using three-electrode system,the electrochemical corrosion resistance properties of five kinds Fe-Al/Cr 3C 2 composite coatings were tested.These were micro Fe-Al/Cr 3C 2 composite coating,nano Fe-Al/Cr 3C 2 composite coating,and composite coating with additional 5%,10%,and 15%nano Fe-Al/Cr 3C 2 reunion-granulation particles,respectively.Zview software was used to fit the AC impedance spectrum in order to analyze the electrochemical corrosion resistance action of coatings.SEM was used to analyze the corrosion surface of coatings.The results indicate that the best electrochemical corrosion resistance property of composite coatings was obtained by adding 5%nano Fe-Al/Cr 3C 2 reunion-granulation particles.Compared with other coatings,the coating with added 5%nano Fe-Al/Cr 3C 2 reunion-granulation particles has maximum self-corrosion potential of-0.775 V and minimum self-corrosion current of 0.280 mA/cm 2.When the content of nano granulated particles is lower than the optimum value,the electrochemical corrosion resistance properties of coatings are because the content of nano granulated particles is too low to improve density and reduce pore size.When the content of nano granulated particles is higher than the optimum value,the electrochemical corrosion resistance property of coatings are nano granulated particles makes surface of coatings showing high chemical energy.

关 键 词：纳米材料 Fe-Al/Cr 3C 2 复合涂层 抗电化学腐蚀 

分 类 号：TB853.29[一般工业技术—摄影技术]