催化裂化重汽油临氢脱砷剂的研究与开发  

Preparation and development of hydrogenation dearsenic catalyst for FCC heavy gasoline

作　　者：鞠雅娜[1] 李天舒 胡亚琼[1] 张然[1] 李阳[1] 姜增琨 冯琪[1] 葛少辉[1] 赵秦峰[1] Ju Yana;Li Tianshu;Hu Yaqiong;Zhang Ran;Li Yang;Jiang Zengkun;Feng Qi;Ge Shaohui;Zhao Qinfeng(PetroChina Petrochemical Research Institute,Beijing 102206,China)

机构地区：[1]中国石油天然气股份有限公司石油化工研究院

出　　处：《工业催化》2019年第10期61-66,共6页Industrial Catalysis

摘　　要：针对催化汽油砷化物脱除需要,开发一种以大孔γ-Al2O3为载体的双金属催化裂化重汽油临氢脱砷剂,并采用XRD和全自动比表面积及孔隙度分析仪对脱砷剂进行表征。考察脱砷剂活性、原料适应性及反应温度、体积空速等工艺条件对脱砷性能的影响。结果表明,该临氢脱砷剂具有较高的脱砷活性(≮85%)和脱砷选择性(≮95%),烯烃基本不饱和;提高反应温度和降低空速有助于提高脱砷剂脱砷活性,烯烃饱和活性基本不受影响。A hydrogenation dearsenic catalyst for FCC heavy gasoline,composed of large poreγ-Al 2O 3 carrier and bimetallic active component,was synthesized.The physical and chemical properties of the catalysts were characterized by XRD and automatic specific surface area and porosity analyzer.The activity of arsenic removal,the adaptability of feed and the influence of reaction temperature and space velocity on catalyst performance were investigated.The results showed that the catalysts exhibited high dearsenic activity(≮85%)and selectivity(≮95%)with little olefin saturation.Increasing the reaction temperature and reducing the space velocity improved the dearsenic activity of the catalysts,and the olefin saturation activity was basically unaffected.

关 键 词：石油化学工程 催化重汽油 临氢脱砷剂 工艺条件 

分 类 号：TE624.43[石油与天然气工程—油气加工工程] TQ426.95[化学工程]