阻聚剂ZJ-701在过氧化物硫化体系胶料中的防焦烧作用研究  被引量:1

Study on Anti-scorching Effect of Polymerization Inhibitor ZJ-701 in Peroxide Cured Compounds

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作  者:杨林 陈勇前 王有治 罗晓锋 黄强 YANG Lin;CHEN Yongqian;WANG Youzhi;LUO Xiaofeng;HUANG Qiang(Chengdu Guibao Science and Technology Co.,Ltd,Chengdu 610041,China)

机构地区:[1]成都硅宝科技股份有限公司

出  处:《橡胶工业》2019年第11期843-847,共5页China Rubber Industry

基  金:国家重点研发计划资助项目(2017YFB0307002);省院省校科技合作研发项目(2017JZ0018)

摘  要:研究阻聚剂ZJ-701在过氧化物硫化体系胶料中的防焦烧作用。结果表明:在甲基乙烯基硅橡胶、丁苯橡胶和三元乙丙橡胶中加入阻聚剂ZJ-701,可以有效延长胶料的焦烧时间,但同时会降低交联效率;阻聚剂ZJ-701的防焦烧效果与橡胶分子链间的交联反应活性有关,反应活性越低,硫化初期的防焦烧效果越好。The anti-scorching effect of polymerization inhibitor ZJ-701 in the peroxide cured compounds was studied.The results showed that,by adding ZJ-701 in methyl vinyl silicone rubber(MVQ),butadiene styrene rubber(SBR)and ethylene propylene terpolymer(EPDM),the scorching time of three compounds was effectively extended,but at the same time the crosslinking efficiency was reduced.The anti-scorching effect of ZJ-701 was related to the cross-linking reaction activity between rubber molecular chains.The lower the reaction activity,the better the anti-scorching effect at the initial vulcanization stage.

关 键 词:阻聚剂 防焦烧作用 过氧化物硫化体系 甲基乙烯基硅橡胶 丁苯橡胶 三元乙丙橡胶 

分 类 号:TQ330.385[化学工程—橡胶工业] TQ330.387

 

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