氨的N—H键活化及其实现的催化有机反应  

N—H Bond Activation of Ammonia for Catalytic Organic Reactions

作　　者：乐传俊[1] 张珂 王晋方[1] 张震威[1] 卞恒伟[1] Yue Chuanjun;Zhang Ke;Wang Jinfang;Zhang Zhenwei;Bian Hengwei(Department of Chemical Engineering,Changzhou Institute of Technology,Changzhou,Jiangsu 213033,China;State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian,Liaoning 116024,China)

机构地区：[1]常州工学院化工系,江苏常州213033 [2]大连理工大学精细化工国家重点实验室,大连辽宁116024

出　　处：《化学世界》2019年第9期553-560,共8页Chemical World

基　　金：江苏省教育厅青蓝工程人才(2016年度)资助项目

摘　　要：分子氨易得、通用,基于氨N—H键活化后参与的有机反应具有理论意义和应用价值。综述了氨的N—H键的活化方式及其在不饱和化学键的氢氨化、芳卤氨化、氨羰基化和氧化偶联等催化有机反应上构建C—N键的进展。Ammonia is facile and versatile so that organic reactions based on the activation of ammonia N—H bond have theoretical significance and application value.We review that the activation of N—H bond on ammonia and the catalytic transformation of hydroamination,aryl amination,amination carbonylation and oxidative coupling for the construction of C—N bond in organic reactions.

关 键 词：氨 N—H键活化 催化氨化 C—N键形成 

分 类 号：TQ2[化学工程—有机化工]