胶乳污泥吸附剂制备及对阳离子染料吸附特性  

Preparation of Latex Sludge Adsorbent and Adsorption Properties of Cationic Dyes

作　　者：于梦楠 柳荣展[2] 刘明明 王冬 张奕 付少海 YU Mengnan;LIU Rongzhan;LIU Mingming;WANG Dong;ZHANG Yi;FU Shaohai(Jiangsu Engineering Research Center for Digital Textile Inkjet Printing(Jiangnan University),Key Laboratory of Eco-Textiles(Jiangnan University),Ministry of Education,Wuxi 214122,China;College of Textiles and Clothing,Qingdao University,Qingdao 266071,China;Wuxi Phoenix Painting Materials Co.,Ltd.,Wuxi 214000,China)

机构地区：[1]江苏省纺织品数字喷墨印花工程技术研究中心(江南大学),生态纺织教育部重点实验室(江南大学),江苏无锡214122 [2]青岛大学纺织服装学院,山东青岛266071 [3]无锡凤凰画材股份有限责任公司,江苏无锡214000

出　　处：《水处理技术》2019年第11期29-34,共6页Technology of Water Treatment

基　　金：中央高校基本科研业务费专项资金资助项目（JUSRP51514）;新工科研究与实践项目（LITE2018-21）;江苏省科技项目（BE2015178）;含毒害组分的典型工业污泥/精馏釜残热化学安全转化与资源化利用（SQ2018YFC190269)

摘　　要：以胶乳生产废水中的污泥为原料,通过热裂解碳化及活化剂活化制备吸附剂。研究了活化剂种类与用量等因素对所制备胶乳污泥吸附剂的影响,对其形貌和组分进行了表征,并用于吸附处理阳离子兰X-GRRL溶液。结果表明,在优化条件下制得的吸附剂为介孔材料,石墨化程度低,有丰富的孔隙结构。在温度为25℃,X-GRRL溶液初始质量浓度250 mg/L、吸附剂投加量1.0 g/L、处理时间360 min时吸附效果为佳,脱色率可达98.57%,吸附量为246.1mg/g。吸附过程较好地符合Langmuir等温吸附模型及准2级反应动力学模型。The adsorbent was prepared by the processes of thermal cracking carbonization and activator activation, sludge from latex production wastewater as the raw material. The effects of type and dosage of activators on the preparation of latex sludge adsorbent were systematically studied. It was characterized and used for treating cationic orchid X-GRRL solution. The results showed that, the adsorbent prepared under optimal conditions was mesoporous material with low degree of graphitization and had abundant pore structures. When temperature, initial mass concentration of X-GRRL, adsorbent dosage and treatment time was 25 ℃, 250 mg/L, 1.0 g/L and 360 min respectively, the adsorption efficiency was the best, the decolorization rate reached 98.57% and adsorption capacity was 246.1 mg/g. The adsorption proc ess was well corresponded to Langmuir isothermal adsorption model and the pseudo-second-order kinetic model.

关 键 词：胶乳生产污泥 吸附剂 阳离子染料 吸附动力学 吸附热力学 

分 类 号：TQ424[化学工程] X791[环境科学与工程—环境工程]