磺化含侧苯基杂萘联苯聚芳醚砜膜材料的制备与性能  

Preparation and properties of sulfonated poly(phthalazinone ether sulfone) containing pendant phenyl groups membrane materials

作　　者：柳周洋 张守海[1,2] 石婉玲 王丹慧 蹇锡高 LIU Zhouyang;ZHANG Shouhai;SHI Wanling;WANG Danhui;JIAN Xigao(School of Chemical Engineering,Dalian University of Technology,Dalian 116024,China;Liaoning High Performance Polymer Engineering Reasearch Center,Dalian 116024,China)

机构地区：[1]大连理工大学化工学院,大连116024 [2]辽宁省高性能树脂工程技术中心,大连116024

出　　处：《膜科学与技术》2019年第5期87-93,100,共8页Membrane Science and Technology

基　　金：国家重点研发计划项目(2017YFB0307600);国家自然科学基金项目(21476038);中央高校基本科研业务费资助项目(DUT17ZD103)

摘　　要：以含侧苯基杂萘联苯聚芳醚砜(PPES Os)为原料,通过非均相法制备磺化含侧苯基杂萘联苯聚芳醚砜(SPPES Os).通过核磁共振与红外光谱表征了SPPES Os的结构,测试了SPPES Os的离子交换容量(IEC)、溶解性,采用热失重分析法对SPPES Os的热稳定性进行了分析.采用溶液浇铸法将SPPES Os制成均质膜,考察了IEC对均质膜的吸水率、溶胀率、接触角、水蒸气吸附性以及水蒸气渗透性能的影响.结果表明,随着IEC增加,膜的吸水率、水蒸气吸附量和水蒸气渗透速率增加,而接触角降低;SPPES Os膜在25℃时吸水率在9%以上,48℃时水蒸气渗透速率高于7.53×10^-3 g/(cm^2 h).Sulfonated poly(phthalazinone ether sulfone)containing pendant phenyl groups(SPPES-Os)was prepared from poly(phthalazinone ether sulfone)containing pendant phenyl groups(PPES-Os)by using heterogenous sulfonation method.The structure of the polymer was confirmed by 1HNMR and FTIR.The solubility of SPPES Os and ion exchange capacity(IEC)of SPPES Os has been tested.The thermal stability of sulfonated polymers was tested by thermogravimetric analysis.The SPPES-Os homogeneous membranes were prepared by solution casting method.The effects of IEC on the water uptake,swelling ratio,contact angle,water vapor adsorption and water vapor permeability of SPPES Os membranes were investigated.Water uptake,water vapor adsorption and water vapor permeability of membranes increased with the increase in IEC,while the contact angle decreased.Water uptake of SPPES Os membranes are above 9.0%at 25℃,and water vapor permeability are above 7.53×10^-3 g/(h·cm^2)at 48℃.

关 键 词：膜材料 磺化 杂萘联苯 聚芳醚砜 水蒸气渗透性 

分 类 号：TQ326.6[化学工程—合成树脂塑料工业]