催化湿式过氧化氢氧化耦合Fe2O3/Al2O3膜分离处理有机废水（英文）  

Catalytic wet peroxide oxidation for organic wastewater treatment by Fe2O3/Al2O3 catalyst coupled with membrane

作　　者：刘祎玮 全燮 陈硕 于洪涛 杜磊 LIU Yiwei;QUAN Xie;CHEN Shuo;YU Hongtao;DU Lei(Key Laboratory of Industrial Ecology and Environmental Engineering,Ministry of Education,Dalian University of Technology,Dalian 116024,China)

机构地区：[1]大连理工大学工业生态与环境工程教育部重点实验室

出　　处：《大连理工大学学报》2019年第6期587-596,共10页Journal of Dalian University of Technology

基　　金：National Natural Science Foundation of China(Major Project:No.21590813);Liaoning Revitalization Talents Program(XLYC1801003)~~

摘　　要：为提高有机废水的降解效率,设计了一种耦合陶瓷管式膜分离和催化湿式过氧化氢氧化(CWPO)技术的反应器.通过溶胶凝胶法将Fe2O3/Al2O3催化剂涂覆到陶瓷管式膜基底上.并通过控制PVA的浓度和涂覆次数,将制备的膜孔径优化到超滤范围.在进行的CWPO实验中,优化了pH、温度、压力和H2O2浓度操作条件.实验表明,在20 mmol/L H2O2,pH=6,90℃和0.4 MPa的反应条件下,苯酚在150 min内能完全降解,TOC去除率为70%.5次连续重复实验和溶出测试表明Fe2O3/Al2O3陶瓷膜具有良好的稳定性和可重复性.该反应器耦合CWPO与膜分离技术为有机废水处理领域提供了新的思路.A reactor coupling catalytic wet peroxide oxidation(CWPO)with ceramic tubular membrane separation was designed for efficiency improvement of degradation of organic wastewater.The membrane was fabricated by coating Fe2O3/Al2O3 on the membrane support by the sol-gel method.The pore size of prepared membrane was optimized to the range of ultrafiltration by controlling PVA concentration and coating times.The CWPO experiment was conducted in various operating conditions to select the optimal pH,working temperature,pressure and H2O2 concentration.The phenol degradation results show complete phenol degradation and 70%TOC removal within 150 min under pH6,90℃,0.4 MPa when the H2O2 concentration is 20 mmol/L.The results of five consecutive and dissolution experiments illustrate good stability and repeatability of the Fe2O3/Al2O3 ceramic membrane.The reactor coupling CWPO with membrane separation presents new insights into the field of organic wastewater treatment.

关 键 词：催化湿式过氧化氢氧化 Fe2O3/Al2O3膜催化剂 苯酚 高级氧化技术 

分 类 号：X703.5[环境科学与工程—环境工程]