有机硅织物增深柔软整理剂的制备  

Preparation of silicone deepening agent for textiles

作　　者：徐山山 彭敏 XU Shan-shan;PENG Min(Zhejiang Gugao Technology Co.,Ltd.,Jiaxing 314000,China;College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310000,China)

机构地区：[1]浙江固高科技有限公司,浙江嘉兴314000 [2]浙江工业大学化学工程学院,浙江杭州310000

出　　处：《印染》2019年第21期23-26,共4页China Dyeing and Finishing

摘　　要：采用八甲基环四硅氧烷(D4)、1,3-二(3-缩水甘油丙基)-1,1,3,3-四甲基二硅氧烷、聚醚二胺与N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷,在催化剂作用下进行开环聚合反应,得到氨基改性增深硅油。通过红外光谱图(IR)和核磁共振氢谱(1H-NMR)结构表征,并进一步对其进行性能研究。结果表明,氨基改性增深硅油与预期目标产物结构一致,整理后的棉织物增深效果有所提升,亲水性基本不变,并具有较好的手感。A new amino modified deepening silicone oil is synthesized through a series of catalysis reac tion using octamethyl cyclotetrasiloxane(D4),1,3-bis(3-glycidoxypropyl)-1,1,3,3-tetramethyldisloxane,polyetheramine,and 3-(β-aminoethyl)-γ-aminopropylmethyldimethoxyl silane as raw materials.The chemical structure is characterized by IR and 1H-NMR.The application properties of the product are stud ied.The results indicate that its structure is consistent with the expected target product.Application re sults show that the deepening effect is obvious,and the treated fabric has similar hydrophilicity and a good hand feeling.

关 键 词：印染助剂 有机硅 增深剂 柔软剂 棉织物 

分 类 号：TS190.2[轻工技术与工程—纺织化学与染整工程]