环保型低温快速化学镀镍磷合金新技术原理及研究进展  

New Technology Principle and Research Progress for Environmental Rapid Electroless Ni-P Plating at Low Temperature

作　　者：李兵 李宁 周保平 杜颖 郑小曈 余刚 LI Bing;LI Ning;ZHOU Bao-ping;DU Ying;ZHENG Xiao-tong;YU Gang(Hunan Liuyuan New Energy Co.,Ltd.,Chenzhou 423038,China;College of Chemistry and Chemical Engineering,Hunan University,Changsha 410082,China)

机构地区：[1]湖南省鎏源新能源有限责任公司,湖南郴州423038 [2]湖南大学化学化工学院,湖南长沙410082

出　　处：《材料保护》2019年第10期116-126,165,共12页Materials Protection

摘　　要：综述了环保低温快速化学镀镍的研究进展,介绍了构筑活性催化镀层的基本原理与方法。对如何提高低温化学镀镍磷合金的沉积速率,获得环保化学镀浴给出了自己的观点。指出酸性和碱性化学镀镍的联用方法能够解决难镀基材化学镀镍问题,表面催化化学镀镍反应是重要提速方法。研究低温快速催化镀镍反应机理可为开发节能环保高效的化学镀镍磷合金催化液奠定理论基础,脉冲化学镀镍对提高生产效率有积极促进作用。应开发镀液再生新技术,使镀浴长期运行,减少废液排放。The research progress of rapid electroless nickel plating in environmental conditions at low temperature was reviewed in this paper.The basic principles and the methods of constructing active catalytic plating were presented,and some advices on how to improve the deposition rate of electroless Ni-P plating at low temperature to obtain environmental electroless bath were put forward. The difficulty of electroless nickel plating on substrates could be solved through the combination of acidic and alkaline methods,and surface catalytic electroless nickel plating was an important accelerating technique. Moreover,the research on the reaction mechanism of fast catalytic nickel plating at low temperature would provide theoretical foundation for development of electroless Ni-P alloy catalytic solution with energy saving,environmentally friendly and high efficiency,and pulse electroless nickel plating played an active role in enhancement of the production efficiency. Furthermore,new technology of plating bath regeneration should be developed to make plating bath working in long-term operation with reduced waste liquid discharge.

关 键 词：化学镀镍磷合金 低温 表面催化镀 次亚磷酸钠 环保工艺 

分 类 号：TQ153.1[化学工程—电化学工业]