酰胺型长链氨烃基改性硅油的合成及表征  

Synthesis and characterization of amide type long chain amino group modified silicone oil

作　　者：刘玉龙 宋秘钊[1] 王娟 LIU Yulong;SONG Mizhao;WANG Juan(The Light Industry and Textile Institute,Qiqihar University,Qiqihar 161006,China)

机构地区：[1]齐齐哈尔大学工业与纺织学院

出　　处：《上海纺织科技》2019年第11期35-37,78,共4页Shanghai Textile Science & Technology

基　　金：黑龙江省自然科学基金项目（B2015018）;黑龙江省省属高等学校基本科研业务费科研项目（B5309479）

摘　　要：以N-(3-二甲氨基丙基)甲基丙烯酰胺为单体,聚甲基氢硅氧烷为聚合物,在氯铂酸-异丙醇催化剂作用下进行硅氢加成反应,合成氨基改性有机硅柔软剂,并对合成物的结构进行IR表征分析。结果表明:N-(3-二甲氨基丙基)甲基丙烯酰胺单体的硅氢加成反应得到了预期设想的合成物,将具有独特性能的氨基基团通过硅氢加成反应接枝到聚甲基氢硅氧烷的侧链上,获得加成产物。With the N-(3-dimethylaminopropyl)methacrylamide as monomer and polymethylhydrogensiloxane as polymer,hydrosilylation reaction is carried out under the action of chloroplatinic acid-isopropanol catalyst to synthesize amino-modified organic Silicon softener and IR characterization of the structure of the composition.The results show that the hydrosilylation reaction of N-(3-dimethylaminopropyl)methacrylamide monomer obtains the expected compound,and the amino group with unique properties is grafted onto the side chain of the polymethylhydrogensiloxane by hydrosilylation reaction,while an addition product is obtained.

关 键 词：N-(3-二甲氨基丙基)甲基丙烯酰胺 聚甲基氢硅氧烷 硅氢加成 改性硅油 有机硅 柔软剂 

分 类 号：TS195.23[轻工技术与工程—纺织化学与染整工程]