多孔配位聚合物:发展历程及研究进展  

Porous coordination polymers: development and research progress

作　　者：钱彬彬 李娜 常泽 卜显和 Binbin Qian;Na Li;Ze Chang;Xian-He Bu(School of Materials Science and Engineering,National Institute for Advanced Materials,Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry,Nankai University,Tianjin 300350,China;State Key Laboratory of Elemento-Organic Chemistry,College of Chemistry,Nankai University,Tianjin 300071,China;Collaborative Innovation Center of Chemical Science and Engineering(Tianjin),Tianjin 300072,China;Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry,Ministry of Education,Tianjin 300387 China)

机构地区：[1]南开大学材料科学与工程学院,国家新材料研究院,天津市金属与分子基材料化学重点实验室,天津300350 [2]南开大学化学学院,元素有机化学国家重点实验室,天津300071 [3]天津化学化工协同创新中心,天津300072 [4]无机有机杂化功能材料化学教育部重点实验室,天津300387

出　　处：《中国科学：化学》2019年第11期1361-1376,共16页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:21421001,21531005);高等学校学科创新引智计划(编号:B18030)资助项目

摘　　要：多孔配位聚合物(PCP)(包括金属有机框架)是一类由金属节点和配体通过配位键连接形成的晶态多孔材料.作为一类新兴的无机-有机杂化材料, PCP具有丰富且可调节的结构和功能,因此其在气体吸附分离、催化、传感等诸多领域展现出巨大的应用潜力,是多学科交叉的研究热点.本文依据PCP的结构及性质特点,总结了第一至第四代多孔配位聚合物PCP研究的发展历程,介绍了该领域的主要研究内容和典型研究进展,进而基于该领域未来面临的挑战和发展趋势分析了材料的实用化前景.Porous coordination polymer(PCP)(including metal-organic framework, MOF) is a kind of crystalline porous material formed by inorganic metal centers and organic ligands through the linkage of coordination interaction.As a new class of inorganic-organic hybrid materials, PCP has various and adjustable structure and functions, so it has great potential application in many fields such as gas adsorption separation, catalysis, sensing, which makes it a multidisciplinary research hot spot. In this review, we summarize the development and research history of the first to fourth generation of PCP on the basis of their distinctive characteristics and properties, and typical research progress in each stage was introduced. Furthermore, the challenges and development trends in this field are presented, and the practical prospects of materials are put forward.

关 键 词：多孔配位聚合物 金属-有机框架 发展历程 应用 

分 类 号：O63[理学—高分子化学]