活性炭表面键合配位体固相萃取填料的制备及其对水中重金属离子吸附性能的研究  

Preparation of activated carbon surface-bonded ligand solid phase extraction packing and its adsorption properties for heavy metal ions in water

作　　者：王荻 申书昌[1] 辛建娇[1] 郑建华 王文波[1] 隋丽丽[1] WANG Di;SHEN Shuchang;XIN Jianjiao;ZHENG Jianhua;WANG Wenbo;SUI Lili(School of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161006,China)

机构地区：[1]齐齐哈尔大学化学与化学工程学院

出　　处：《黑龙江大学自然科学学报》2019年第5期590-596,共7页Journal of Natural Science of Heilongjiang University

基　　金：国家自然科学基金资助项目(51802167);黑龙江省自然科学基金资助项目(QC2018015);黑龙江省省属高等学校基本科研业务费科研项目(135109206);齐齐哈尔大学研究生创新科研项目(YJSCX2018-021X)

摘　　要：以椰子壳为原料,经过磷酸活化制得活性炭,键合苯甲酰异硫氰酸酯制得表面键合配位体改性活性炭固相萃取材料。利用N2吸附-脱附、SEM、XPS、FT-IR等手段对所制备的固相萃取填料进行表征,考察了其对Zn^2+、Mn^2+、Pb^2+、Cd^2+和Ag^+金属离子的吸附性能。结果表明,该固相萃取填料对Zn^2+、Mn^2+、Pb^2+、Cd^2+和Ag^+的吸附容量分别为12.86、11.27、10.91、10.13和9.87mg·g^-1。以5mol·L^-1HNO3+0.05mo·L^-1乙二胺四乙酸二钠溶液作为洗脱液对吸附的金属离子进行洗脱,通过固相萃取(SPE)与电感耦合等离子体质谱(ICP-MS)联用测定水样中重金属离子的含量,Zn^2+、Mn^2+、Pb^2+、Cd^2+和Ag^+的检出限分别为0.147、0.177、0.185、0.228和0.249mg·L^-1。The solid phase extraction material of surface-bonded ligand-modified activated carbon was obtained after the raw material of coconut shell was activated by phosphoric acid and then was bonded by benzoyl isothiocyanate.The resultant materials were characterized by means of nitrogen adsorption and desorption,SEM,XPS and FT-IR,and their adsorption properties for Zn^2+,Mn^2+,Pb^2+,Cd^2+and Ag+were investigated.The adsorption capacities of the prepared solid phase extraction fillers for five metal ions were 12.86,11.27,10.91,10.13 and 9.87 mg·g^-1.The 5 mol·L^-1 HNO 3 and 0.05 mol·L^-1 disodium edetate solution was used as eluent to elute the metal ions.The content of heavy metal ions in the water sample was determined by SPE-ICP-MS.The detection limits of Zn^2+,Mn^2+,Pb^2+,Cd 2+and Ag+were 0.147,0.177,0.185,0.228 and 0.249 mg·L^-1,respectively.

关 键 词：活性炭键合配位体 固相萃取 重金属离子 电感耦合等离子体质谱 

分 类 号：O652.6[理学—分析化学]