Metal-free acyl-directed electrophilic C–H borylation using just BBr3  

作　　者：Michael J.Ingleson 

机构地区：[1]School of Chemistry, University of Edinburgh

出　　处：《Science China Chemistry》2019年第12期1547-1548,共2页中国科学（化学英文版）

基　　金：supported by the Horizon 2020 Research and Innovation Program (769599)

摘　　要：The considerable utility of organoboranes in synthesis is firmly established,which is in a large part due to the power of the Suzuki-Miyaura cross-coupling reaction for con・structing C-C bonds.Therefore,discovering simple new routes to form desirable organoboranes continues to be of significant import.Methodologies that directly transform C-H into C-B are particularly desirable,especially if borylation occurs with excellent site selectivity and without precious metal catalysts due to their low crustal abundance,high cost and toxicity.

关 键 词：desirable organo BONDS 

分 类 号：O64[理学—物理化学]