Water-Based Processing of Fiberboard of Acrylic Resin Composites Reinforced With Cellulose Wood Pulp and Cellulose Nanofibrils  

作　　者：Emanoele Maria Santos Chiromito Eliane Trovatti Antonio Jose Felix Carvalho 

机构地区：[1]Department of Materials Engineering,São Carlos School of Engineering,University of São Paulo,Av.João Dagnone,1100,13563-120,São Carlos-SP-Brazil [2]University of Araraquara-UNIARA,R.Carlos Gomes,1217,CEP 14801-320,Araraquara,SP,Brazil

出　　处：《Journal of Renewable Materials》2019年第5期403-413,共11页可再生材料杂志（英文）

摘　　要：Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics,its use is limited due to its tendency to form agglomerates and due to its high hydrophilic character.Here we describe fiberboard composites with high contents of wood pulp or cellulose nanofibrils,and a resin of poly(styrene-methyl-methacrylate-acrylic acid)used as water-based emulsion.Cellulose wood pulp and cellulose nanofibrils were used directly in the form of water suspensions.The method is based on the flocculation of the polymer emulsion followed by agglomeration of a mixture of the polymer emulsion and cellulose suspension,leading to the co-precipitation of the composite material,which can be easily separated from the water phase.Composites with acrylic polymer/cellulose fibers in the proportions of 75:25,50:50 and 25:75 wt%were prepared.Composites were characterized by scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FTIR),thermogravimetric analysis(TGA),dynamic mechanical analysis(DMA)and water absorption tests.SEM analysis revealed a very good dispersion of the fibers without evidence of agglomeration,which led to superior mechanical properties.These results showed the effectiveness of the methodology and the potential of cellulose wood pulp and CNF as reinforcement fillers in fiberboard composites and any other high fiber-content materials.

关 键 词：Cellulose wood pulp cellulose nanofibrils COMPOSITES acrylic resin emulsion FIBERBOARD 

分 类 号：O63[理学—高分子化学]